The Chemistry Maths Book, Second Edition

(Grace) #1

86 Chapter 3Transcendental functions


The pH is an example of the use of the logarithm as a scale of measure. Other


examples of logarithmic scales are the Richter scale for the ‘strength of earthquake’,


the bel scale of loudness, and the scale of star magnitudes.


0 Exercises 40–42


Conversion factors


The logarithm occurs in a number of expressions for physical properties and


processes, and the ordinary logarithm is still sometimes found, instead of the natural


logarithm, in the scientific literature and in textbooks. In general, the conversion


factor from one base, a, to another, b, is given by


log


b

x 1 = 1 log


b

a 1 × 1 log


a

x (3.42)


Thus, if x 1 = 1 a


y

, then


log


a

x 1 = 1 y


log


b

x 1 = 1 log


b

a


y

1 = 1 y 1 log


b

a 1 = 1 (log


a

x) 1 × 1 (log


b

a)


The conversion factors between ordinary and natural logarithms are therefore


lg 1 x 1 = 1 log


10

x 1 = 1 log


10

e 1 × 1 log


e

x 1 ≈ 1 0.43429448 1 × 1 log


e

x


ln 1 x 1 = 1 log


e

x 1 = 1 log


e

101 × 1 log


10

x 1 ≈ 1 2.30258093 1 × 1 log


10

x


3.8 Values of exponential and logarithmic functions


Table 3.3 shows values ofln 1 x, x 1 ln 1 x, e


x

, ande


−x

for a wide range of values of x.


Table 3.3


x ln 1 xx 1 ln 1 xe


x

e


−x

0–∞ 01 1


   


slowly


   


10


− 6

−13.8 −0.00001 1.000001 0.9999990


10


− 3

−6.9 −0.007 1.001 0.9990


1 0 0 2.7 0.37


10 2.3 23 21 × 110


4

51 × 110


− 5

10


2

4.6 460 31 × 110


43

41 × 110


− 44

10


3

6.9 6908 


   


slowly fast fast


   


∞∞ ∞ ∞ 0

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