Fundamentals of Medicinal Chemistry

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elimination of a drug from a defined region of the body to the plasma concen-

tration of that drug. For example, the total clearance (ClT), that is, the volume

of blood in the whole body cleared of a drug in unit time, is related to the rate of

elimination by the equation:

rate of elimination of a drug from the whole body¼ClTCp (8:8)

The clearance of a drug from a specific region of the body is the sum of all

the clearances of all the contributing processes in that region. For example,

hepatic clearance (ClH) is the sum of the clearances due to metabolism (ClM) and

excretion (ClBile) in the liver, that is:

ClH¼ClMþClBile (8:9)

However, it is emphasized that clearance is an artificial concept as it is not

possible for a drug to be removed from only one part of the total volume of the

blood in the body or organ.

For elimination processes exhibitingfirst order kineticsit can be shown that

clearance is related toVd,kelandt1/2by the mathematical expressions:

ClT¼kelVd (8:10)

and

ClT¼Vd

0 : 693

t 1 = 2

(8:11)

Since botht1/2andkelare constant for elimination processesfollowing first

order kinetics, Cl will also be constant. However, should the order of the

elimination change due to a change in the biological situation, such as the

drug concentration increasing to the point where it saturates the metabolic

elimination pathways, then clearance may not be constant.

For an IV bolus, which places the drug directly in the circulatory system, total

clearance (ClT) of the drug from the body can also be determined from the plots

ofCpagainstt. The area under the curve (AUC) represents the total amount of

the drug that reaches the circulatory system in timet. It is related to the dose

administered by the relationship:

dose¼ClTAUC (8:12)

This relationship holds true regardless of the way in which a single dose of the

drug is administered. However, for enteral routes the dose is the amount

INTRAVASCULAR ADMINISTRATION 167

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