Physical Chemistry , 1st ed.

804 APPENDIXES

Source:D. R. Lide, ed.,CRC Handbook of Chemistry and Physics,CRC Press, Boca Raton, Fla., 2001. Reprinted with

permission.

2

Wavelength (

m)

Wavenumber (cm

^1

)

16

4000

4000

650

700

800

900

1000

1500

2000

2500

34567

9

81

0

11

12

13

14

15

Miscellaneous SulfurOxygenCompounds PhosphorusOxygen CarbonOxygen NitrogenOxygen Assignments

W

SH

SiH

PH

M M

M

M

M

S

S

S

S

SS

M

M

SS

S

S

S

S S

S

S

S S

S S

SS

S S

SMS

M

Epoxy ring

M

M

W

SH

M

S

S S

S

S

S

S

SSS

CO

(^23)
(R –
O)
P 2
O
OR
NO
2
OR
O Str.C
O Str.C
N Str.C
N Str.C
C Str.
CH RockNH Rock
C
C Str.NH Bend
CH Bend
CH Bend
C
NO
NOR
R
NO
NO 2
(^13)

• 
  

CO

R)

2

(O

CHN

R)

2

(O

CH

2

P

O

O

PO

O

SO

(^24)

• OSO

2

R

OR

OSO

2

R

R

SO

2

NH

2

R SO

2

R

R

SOR

SO R

(^13)

• 
  

R

SO

HR 3

C

XX

(Isocyanates)

Sulfur groupsPhosphorusSiliconFluorine ChlorineBromine

Ionic sulfateIonic sulfonateSulfonic acidCovalent sulfateCovalent sulfonateSulfonamideSulfoneSulfoxideIonic phosphate PO

(^34)

• 
  

Covalent phosphateIonic carbonateImino carbonateIonic nitrateCovalent nitrateNitroCovalent nitriteNitrosoAmmonium NH

+ 4

OH and PH Str.

CH Str.

Unconj.Conj.

Covalent carbonate

" " " "

OCC

P^2

S

Si CH

3

CF

and CF 2

3

CH

2

O

(Si, P, or S)

CH

2

S

CH

2

Strained ring

(Lactams)

CO

C

Chlorocarbonate

O

C

Acid chloride

O

CSi

SC

OP

C

F (Sat.)

F (Unsat.)

C

CCI

and CCI 2

3

CCI

(Aliph.)

CBr

and CBr 2

3

CBr (Aliph.)

C

X Str.

LegendS = StrongM = MediumW = Weak

Copyright

2011

Cengage

Learning.

All

Rights

Reserved.

May

not

be

copied,

scanned,

or

duplicated,

in

whole

or

in

part.