Assume that we canfactorizethe solution between time and space.
ψ(x,t) =u(x)T(t)
Plug this into the Schr ̈odinger Equation.
(
− ̄h^2
2 m
∂^2 u(x)
∂x^2
+V(x)u(x)
)
T(t) =i ̄hu(x)
∂T(t)
∂t
Put everything that depends onxon the left and everything that depends onton the right.
(
−h ̄^2
2 m
∂^2 u(x)
∂x^2 +V(x)u(x)
)
u(x)
=
i ̄h∂T∂t(t)
T(t)
=const.=E
Since we have a function of onlyxset equal to a function of onlyt, theyboth must equal a
constant. In the equation above, we call the constantE, (with some knowledge of the outcome).
We now have an equation intset equal to a constant
i ̄h
∂T(t)
∂t
=E T(t)
which has a simplegeneral solution,
T(t) =Ce−iEt/ ̄h
and an equation inxset equal to a constant
− ̄h^2
2 m
∂^2 u(x)
∂x^2
+V(x)u(x) =E u(x)
which depends on the problem to be solved (throughV(x)).
Thexequation is often called theTime Independent Schr ̈odinger Equation.
− ̄h^2
2 m
∂^2 u(x)
∂x^2
+V(x)u(x) =E u(x)
Here,Eis a constant. Thefull time dependent solutionis.
ψ(x,t) =u(x)e−iEt/ ̄h
- See Example 7.6.1:Solve the Schr ̈odinger equation for a constant potentialV 0 .*
7.5 Derivations and Computations
7.5.1 Linear Operators
Linear operatorsLsatisfy the equation