15.4 Particle in a Sphere*
This islike the particle in a boxexcept now the particle is confined to the inside of a sphere of
radiusa. Inside the sphere, the solution is a Bessel function. Outside the sphere, the wavefunction
is zero. The boundary condition is that the wave function go to zeroon the sphere.
jℓ(ka) = 0
There are an infinite number of solutions for eachℓ. We only need to find the zeros of the Bessel
functions. The table below gives the lowest values ofka=
√
2 ma^2 E
̄h^2 which satisfy the boundary
condition.
ℓ n= 1 n= 2 n= 3
0 3.14 6.28 9.42
1 4.49 7.73
2 5.72 9.10
3 6.99 10.42
4 8.18
5 9.32
We can see bothangular and radial excitations.
15.5 Bound States in a Spherical Potential Well*
We now wish to find theenergy eigenstatesfor a spherical potential well of radiusaand potential
−V 0.
Spherical Potential Well (Bound States)
V(r)
r
a
-V 0
E
We must use the Bessel function near the origin.
Rnℓ(r) =Ajℓ(kr)
k=
√
2 μ(E+V 0 )
̄h^2