where
ρ=
2 Z
na 0
r
and the coefficients come from the recursion relation
ak+1=
k+ℓ+ 1−n
(k+ 1)(k+ 2ℓ+ 2)
ak.
The series terminates fork=n−ℓ−1.
Lets start withR 10.
R 10 (r) =ρ^0
∑^0
k=0
akρke−ρ/^2
R 10 (r) =Ce−Zr/a^0
We determineCfrom the normalization condition.
∫∞
0
r^2 R∗nℓRnℓdr= 1
|C|^2
∫∞
0
r^2 e−^2 Zr/a^0 dr= 1
This can be integrated by parts twice.
2
(a
0
2 Z
) 2
|C|^2
∫∞
0
e−^2 Zr/a^0 dr= 1
2
(a
0
2 Z
) 3
|C|^2 = 1
C^2 =
1
2
(
2 Z
a 0
) 3
C=
1
√
2
(
2 Z
a 0
) (^32)
R 10 (r) = 2
(
Z
a 0
) (^32)
e−Zr/a^0
R 21 can be computed in a similar way. No recursion is needed.
Lets tryR 20.
R 20 (r) =ρ^0
∑^1
k=0
akρke−ρ/^2
R 20 (r) = (a 0 +a 1 ρ)e−ρ/^2