130_notes.dvi

(Frankie) #1

where


ρ=

2 Z

na 0
r

and the coefficients come from the recursion relation


ak+1=

k+ℓ+ 1−n
(k+ 1)(k+ 2ℓ+ 2)

ak.

The series terminates fork=n−ℓ−1.


Lets start withR 10.


R 10 (r) =ρ^0

∑^0

k=0

akρke−ρ/^2

R 10 (r) =Ce−Zr/a^0

We determineCfrom the normalization condition.


∫∞

0

r^2 R∗nℓRnℓdr= 1

|C|^2

∫∞

0

r^2 e−^2 Zr/a^0 dr= 1

This can be integrated by parts twice.


2

(a
0
2 Z

) 2

|C|^2

∫∞

0

e−^2 Zr/a^0 dr= 1

2

(a
0
2 Z

) 3

|C|^2 = 1

C^2 =

1

2

(

2 Z

a 0

) 3

C=

1


2

(

2 Z

a 0

) (^32)
R 10 (r) = 2


(

Z

a 0

) (^32)
e−Zr/a^0
R 21 can be computed in a similar way. No recursion is needed.
Lets tryR 20.
R 20 (r) =ρ^0


∑^1

k=0

akρke−ρ/^2

R 20 (r) = (a 0 +a 1 ρ)e−ρ/^2
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