and that angular momentum is quantizedsuch thatL=n ̄h, forn= 1, 2 , 3 .... This is natural
since ̄hhas units of angular momentum. Bohr correctly postdicted the Hydrogen energies and the
size of the atom.
Balance of forces for circular orbits.
mv^2
r
=
1
4 πǫ 0
e^2
r^2
Angular momentum quantization assumption.
L=mvr=n ̄h
Solve for velocity.
v=
n ̄h
mr
Plug into force equation to get formula forr.
mn^2 ̄h^2 r^2
m^2 r^2 r
=
e^2
4 πǫ 0
n^2 ̄h^2
mr
=
e^2
4 πǫ 0
1
r
=
me^2
4 πǫ 0 ̄h^2
1
n^2
Now we just want to plugvandrinto the energy formula. We write the Hydrogen potential in
terms of the fine structure constant (See section 2.5.2): αSI= 4 πǫ^10 e
2
̄hc≈
1
137.
V(r) =
−α ̄hc
r
1
r
=
αmc
̄h
1
n^2
We now compute the energy levels.
E =
1
2
mv^2 +V(r)
E =
1
2
m
(
n ̄h
mr
) 2
−
α ̄hc
r
E =
1
2
m
(
αn ̄hc
n^2 ̄h
) 2
−
α^2 ̄hmc^2
n^2 ̄h
E =
1
2
m
(αc
n
) 2
−
α^2 mc^2
n^2
E =
1
2
(
α^2 mc^2
n^2
)
−
α^2 mc^2
n^2
=−
α^2 mc^2
2 n^2
The constant α
(^2) mc 2
2 =
511000
2(137)^2 = 13.6 eV. Bohr’s formula gives theright Hydrogen energy
spectrum.