130_notes.dvi

(Frankie) #1

and that angular momentum is quantizedsuch thatL=n ̄h, forn= 1, 2 , 3 .... This is natural
since ̄hhas units of angular momentum. Bohr correctly postdicted the Hydrogen energies and the
size of the atom.


Balance of forces for circular orbits.
mv^2
r


=

1

4 πǫ 0

e^2
r^2

Angular momentum quantization assumption.


L=mvr=n ̄h

Solve for velocity.


v=

n ̄h
mr

Plug into force equation to get formula forr.


mn^2 ̄h^2 r^2
m^2 r^2 r

=

e^2
4 πǫ 0
n^2 ̄h^2
mr

=

e^2
4 πǫ 0
1
r

=

me^2
4 πǫ 0 ̄h^2

1

n^2

Now we just want to plugvandrinto the energy formula. We write the Hydrogen potential in
terms of the fine structure constant (See section 2.5.2): αSI= 4 πǫ^10 e


2
̄hc≈

1
137.

V(r) =

−α ̄hc
r
1
r

=

αmc
̄h

1

n^2

We now compute the energy levels.


E =

1

2

mv^2 +V(r)

E =

1

2

m

(

n ̄h
mr

) 2


α ̄hc
r

E =

1

2

m

(

αn ̄hc
n^2 ̄h

) 2


α^2 ̄hmc^2
n^2 ̄h

E =

1

2

m

(αc
n

) 2


α^2 mc^2
n^2

E =

1

2

(

α^2 mc^2
n^2

)


α^2 mc^2
n^2

=−

α^2 mc^2
2 n^2

The constant α


(^2) mc 2
2 =
511000
2(137)^2 = 13.6 eV. Bohr’s formula gives theright Hydrogen energy
spectrum.

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