To solve (12.3) perturbatively, we move the perturbative correction piece to the right hand side
of the equation,
(H 0 −E)|ψk〉=−λH 1 |ψk〉 (12.4)
The operatorH 0 −Eis not quite invertible, and precisely has the states|φk〉for its null-space. In
the case of bound state perturbation theory, we remedied this situation byinvertingH 0 −Eon
the subspace of the Hilbert space orthogonal to the its null-space. This was possible because the
null-space consisted of discrete states. In the case of the continuous spectrum, the natural way of
dealing with the null-space is as follows. We add a small imaginary partiεto the energyE. Since
H 0 is self-adjoint, all its eigenvalues are real, and thus the modified operatorH 0 −E±iεwill now
be invertible, although the eigenvalue corresponding to states|φk〉in the null-space will be tiny.
This procedure naturally produces two solutions to (12.3) and (12.4), given by
|ψ±k〉=|φk〉−
λ
H 0 −E∓iε
H 1 |ψk±〉 ε > 0 (12.5)
This equation is known as theLippmann-Schwinger equation. (Later on, we shall use an even more
drastic extension of this equation and letz=E±iεtake arbitrary values in the complex plane.)
Althoughεwas introduced here as a finite real positive number, it is understood that one must
take the limitε→0. To understand thisiεprescription in more detail, it will be helpful to study
its mathematical properties in some detail.
12.2 Theiεprescription
Theiεprescription is given by the limit
lim
ε→ 0
1
x−iε
x∈R, ε > 0 (12.6)
should be understood as a generalized function (ordistribution) similar to the Diracδ-function. In
fact, it contains aδ-function, as may be seen by separating its real and imaginary parts,
1
x−iε
=
x
x^2 +ε^2
+
iε
x^2 +ε^2
(12.7)
The limit of the first term is, by definition, the sl principal value prescription PV(1/x), while the
limit of the second may be found by integrating it against a smooth test functionf(x),
lim
ε→ 0
∫
R
dx
iε
x^2 +ε^2
f(x) = lim
ε→ 0
∫
R
dx
i
x^2 + 1
f(εx) =iπf(0) (12.8)
Hence the limit of the second term is given byiπδ(x). Putting all together, we obtain,
lim
ε→ 0
1
x−iε
= PV
1
x
+iπδ(x) (12.9)
This clearly demonstrates that the limit is a generalized function. It is customary when writing
theiεprescription to simply omit the limε→ 0 symbol in front.