QuantumPhysics.dvi

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4.3 Expectation values and quantum fluctuations


If|φ〉is an eigenstate of an observableAwith eigenvaluea, then the probability for the


outcomeain a measurement ofAis unity. If|φ〉is not an eigenstate ofA, then|φ〉cannot


be associated with any one of the eigenvalues ofA, but there is still a probabilistic expectation


value for the observableA. For a general state|φ〉, any of the eigenvaluesaiofAmay be


the outcome of a measurement ofA, but only with a certain probabilityp(ai|φ), computed


in the preceding subsection. The expected outcome in the state|φ〉of a measurement onA


is then the probabilistic expectation value for any of the eigenvaluesai, given by



i

aip(ai|φ) =



i

ai〈φ|Pi|φ〉=〈φ|A|φ〉 (4.15)


The quantity〈φ|A|φ〉, also denoted by〈A〉φ, is referred to asthe expectation value ofAin


the state|φ〉. As before, it is being assumed that||φ||= 1.


In probability theory one is interested in the standard deviation away from an average.


Similarly, in quantum physics one is interested in theaverage quantum fluctuations away


from an expectation value. One defines the strength of these quantum fluctuations as follows.


For any given state|φ〉, subtract the expectation value of the observable to define a new


observable which has vanishing expectation value (still in the state|φ〉),


Aφ≡A−〈A〉φIH 〈φ|Aφ|φ〉= 0 (4.16)


The magnitude of the quantum fluctuations is then defined by


(∆φA)^2 ≡〈φ|(Aφ)^2 |φ〉=



i

(

ai−〈A〉φ


) 2

p(ai|φ) (4.17)


Of course, for|φ〉an eigenstate of the observable A, we have ∆φA= 0, and there are no


quantum fluctuations of the observableAin this state.


4.4 Incompatible observables, Heisenberg uncertainty relations


Compatible observables may be measured simultaneously on all states. In particular, this


means that we can simultaneously have


∆φA= ∆φB= 0 (4.18)


for one and the same state|φ〉, which is then an eigenstate of bothAandB.


How about two incompatible observables,AandB, characterized by [A,B] 6 = 0? Al-


though incompatible observables cannot be measured simultaneously on all states,it may or


may not be possible to measureAandBsimultaneously on some subset of all the states.

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