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FIRST LAW OF THERMODYNAMICS 195

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/M-therm/Th4-5.pm5

Fig. 4.64
The constant is either p 1 v 1 or p 2 v 2

i.e., W = 5.5 × 10^5 × 0.3427 × loge

p
p

1
2

Q pv 11 pv2 2 vv^2 pp
1

1
2

L =
NM

O
QP

or =

= 5.5 × 10^5 × 0.3427 × loge
5.
.75

5
0

F
HG

I
KJ = 375543 N-m/kg.
Using non-flow energy equation, we get
Q = (u 2 – u 1 ) + W

= 2.25 +
375543
103 = 378 kJ/kg
i.e., Heat supplied = 378 kJ/kg. (Ans.)


Example 4.56. Dry saturated steam at 100 bar expands isothermally and reversibly to a
pressure of 10 bar. Calculate per kg of steam :
(i)The heat supplied ;
(ii)The work done.
Solution. Initial pressure of steam, p 1 = 100 bar
Final pressure of steam, p 2 = 10 bar
The process is shown in Fig. 4.65, the shaded area representing the heat supplied.
At 100 bar, dry saturated : From steam tables,
s 1 = sg = 5.619 kJ/kg K and ts 1 = 311°C
At 10 bar and 311°C the steam is superheated, hence interpolating


s 2 = 7.124 +

311 300
350 300



F
H

I
K (7.301 – 7.124) or s^2 = 7.163 kJ/kg K.
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