274 ENGINEERING THERMODYNAMICSdharm
/M-therm/th5-4.pm5Note that if in this problem sA – s 2 happened to be greater than sA – s 1 , this would mean that
s 1 was greater than s 2 , and the process should appear as in Fig. 5.36.
Note. The change of entropy can also be found by using the following relation :s 2 – s 1 = cvn
n−
−F
HGI
KJγ
1 loge^T
T2
1= 0.71825 399
25 1−
−F
HGI
KJ loge^597.3
873F
HGI
KJ Qγ= = =L
NM
O
QP
c
cp
v- (^005) 1.
0718
399
.
= 0.718 × (– 0.596) × (– 0.3795) = 0.1626 kJ/kg K (increase).
Example 5.28. In an air turbine the air expands from 7 bar and 460°C to 1.012 bar and
160 °C. The heat loss from the turbine can be assumed to be negligible.
(i)Show that the process is irreversible ;
(ii)Calculate the change of entropy per kg of air.
Solution. Refer Fig. 5.37.
Initial pressure, p 1 = 7 bar = 7 × 10^5 N/m^2
Initial temperature, T 1 = 460 + 273 = 733 K
Final pressure, p 2 = 1.012 bar = 1.012 × 10^5 N/m^2
Final temperature, T 2 = 160 + 273 = 433 K
Fig. 5.37
(i)To prove that the process is irreversible :
Since the heat loss is negligible, the process is adiabatic.
For a reversible adiabatic process for a perfect gas, using the following equation, we have :
T
T
2
1 =
p
p
2
1
1
F
HG
I
KJ
−γ
γ
T 2
733 =
1.4
012 1.4
7
1
F
HG
I
KJ
F −
HG
I
KJ