TITLE.PM5

342 ENGINEERING THERMODYNAMICS

dharm
\M-therm\Th7-1.pm5

Then the differential of the dependent variable x is given by

dx =

∂

∂

∂

∂

x

y

dy x

z z y

F

HG

I

KJ

+F

HG

I

KJ^ dz ...(7.2)

where dx is called an exact differential.

If

∂

∂

x

y z

F

HG

I

KJ = M and

∂

∂

x

z y

F

HG

I

KJ = N

Then dx = Mdy + Ndz ...(7.3)

Partial differentiation of M and N with respect to z and y, respectively, gives

∂

∂

∂

∂∂

M

z

x

yz

=

2

and

∂

∂

∂

∂∂

N

y

x

zy

=

2

or

∂

∂

∂

∂

M

z

N

y

= ...(7.4)

dx is a perfect differential when eqn. (7.4) is satisfied for any function x.

Similarly if y = y(x, z) and z = z(x, y) ...(7.5)

then from these two relations, we have

dy =

∂

∂

y

x z

F

HG

I

KJ^ dx +

∂

∂

y

z x

F

HG

I

KJ^ dz ...(7.6)

dz =

∂

∂

z

x y

F

HG

I

KJ^ dx +

∂

∂

z

y x

F

HG

I

KJ^ dy ...(7.7)

dy =

∂

∂

y

x z

F

HG

I

KJ^ dx +

∂

∂

y

z x

F

HG

I

KJ^

∂

∂

∂

∂

z

x

dx z

y

dy

y x

F

HG

I

KJ

+

F

HG

I

KJ

L

N

M

M

O

Q

P

P

=

∂

∂

∂

∂

∂

∂

y

x

y

z

z

zxx y

F

HG

I

KJ

+F

HG

I

KJ

F

HG

I

KJ

L

N

M

M

O

Q

P

P^ dx +

∂

∂

∂

∂

y

z

z

x y x

F

HG

I

KJ

F

HG

I

KJ^ dy

=

∂

∂

∂

∂

∂

∂

y

x

y

z

z

zxx y

F

HG

I

KJ

+F

HG

I

KJ

F

HG

I

KJ

L

N

M

M

O

Q

P

P^ dx + dy

or

∂

∂

∂

∂

∂

∂

y

x

y

z

z

zxx y

F

HG

I

KJ

+F

HG

I

KJ

F

HG

I

KJ = 0

or

∂

∂

∂

∂

y

z

z

x x y

F

HG

I

KJ

F

HG

I

KJ = –

∂

∂

y

x z

F

HG

I

KJ

or

∂

∂

∂

∂

∂

∂

x

y

z

x

y

z y z x

F

HG

I

KJ

F

HG

I

KJ

F

HG

I

KJ = – 1 ...(7.8)

In terms of p, v and T, the following relation holds good

∂

∂

∂

∂

∂

∂

p

v

T

p

v

T v T p

F

HG

I

KJ

F

HG

I

KJ

F

HG

I

KJ = – 1 ...(7.9)