98 CHAPTER 3. CHARGE TRANSPORT IN MATERIALS
How strongly V(r) couples
the initial and final states
How many final states there
are to scatter into
SCATTERING RATE
Initial electron Final electron
SCATTERING POTENTIAL
V(r)
k k'
+
Figure 3.6: Scattering of an electron initially with momentumkfrom a scattering potential
V(r). The final momentum isk′. The scattering process is assumed to be instantaneous.
•|Mij|^2 : The quantity is called the matrix element of the scattering and is given by
Mij=
∫
ψf∗V(r)ψid^3 r (3.3.8)
The matrix element tells us how the potential couples the initial and the final state. A stronger
coupling causes a higher rate of scattering.
- δ(Ei±ω−Ef):Thisδ-function is simply a representative of energy conservation. The
process where
Ef=Ei+ω (3.3.9)
is called absorption, while the process
Ef=Ei−ω (3.3.10)