100 CHAPTER 3. CHARGE TRANSPORT IN MATERIALS
Optical mode
Acoustical mode
k
k
16
14
12
10
6
8
4
2
0
0.06
0.05
0.04
0.03
0.02
0.01
0
0 [100] 1.0
TO
LO
GaAs
LA
TA
FREQUENCY
v
(10
12
Hz)
REDUCED WAVE NUMBERk/Kmax
ENERGY
(eV)
(a)
(b)
The two atoms
on the unit cell
vibrate in
opposing motion.
The two atoms
in the unit cell
vibrate along the
same direction.
- –
- –
- –
- –
Figure 3.7: (a) Typical frequency-wavenumber relations of a semiconductor (GaAs in this case).
(b) The displacement of atoms in the optical and acoustic branches of the vibrations is shown.
The motion of the atoms is shown for smallkvibrations.
whereDis called a deformation potential (units are eV) and∂u∂xis the amplitude gradient of the
atomic vibrations.
The optical phonons produce a potential disturbance, which is proportional to the atomic
vibration amplitude, since in the optical vibrations the two atoms in the basis vibrate opposing