134 CHAPTER 3. CHARGE TRANSPORT IN MATERIALS
σn[cm-2]TrapFigure 3.23: Picture of the capture cross sectionCase 1vth x 0Case 2 ΔL 2ΔL 2ΔL 3ΔL 3Path in the
absence of trapFigure 3.24: Electrons within the “volume” above will be captured by the trapcloser) would have intersected the capture cross section and be captured. Hence all electrons
in the volumeV =σn·vthwill be captured each second by available empty traps. Thus the
number of electrons available to be captured per second is
nσnvth (3.8.25)and recalling the concentration of available empty traps isNt(1−f), then the rate,racan be
written:
ra=vthσnnNt(1−f) (3.8.26)
OR, the proportionality constant isσnvth(for the rate of electron capture)
vth=√
2 E
m∗=
√
2 ·
3 kBT
2 m∗