518 APPENDIX B. BOLTZMANN TRANSPORT THEORY
n(r)
Position
Time t = 0
r =δtvk
n(r)
Position
Time t =δt
δtvk
r
Figure B.1: At timet=0particles at positionr−δtvkreach the positionrat a later timeδt.
This simple concept is important in establishing the Boltzmann transport equation.
- Due to the motion of the electrons (diffusion), carriers will be moving into and out of any
volume element aroundr. - Due to the influence of external forces, electrons will be changing their momentum (or
k-value) according todk/dt=Fext. - Due to scattering processes, electrons will move from onek-state to another.
We will now calculate these three individual changes by evaluating the partial time derivative
of the functionfk(r)due to each source.
B.1.1 Diffusion-Induced Evolution offk(r) ...................
Ifvkis the velocity of a carrier in the statek, in a time intervalt, the electron moves a distance
tvk. Thus the number of electrons in the neighborhood ofrat timeδtis equal to the number of
carriers in the neighborhood ofr−δtvkat time 0, as shown in figure B.1
We can thus define the following equality due to the diffusion
fk(r,δt)=fk(r−δtvk,0) (B.2)
or
fk(r,0) +
∂fk
∂t
·δt = fk(r,0)−
∂fk
∂r
·δtvk
∂fk
∂t
∣∣
∣∣
diff
= −
∂fk
∂r
·vk (B.3)