B.1. BOLTZMANN TRANSPORT EQUATION 523
eτE
h
fk
0
0 )
eτE
h
f^0 k)–
Figure B.3: The displaced distribution function shows the effect of an applied electric field.
and negative velocities. When the field is applied, there is a net shift in the electron momenta
and velocities given by
δp = δk=−eτE
δv = −
eτE
m∗
(B.22)
This gives, for the mobility,
μ=
eτ
m∗
(B.23)
If the electron concentration isn, the current density is
J = neδv
=
ne^2 τE
m∗
or the conductivity of the system is
σ=
ne^2 τ
m∗
(B.24)
This equation relates a microscopic quantityτto a macroscopic quantityσ.
So far we have introduced the relaxation timeτ, but not described how it is to be calculated.
We will now relate it to the scattering rateW(k,k
′
), which can be calculated by using the Fermi
golden rule. We have, for the scattering integral,
∂f
∂t
)
scattering
=
∫ [
f(k
′
)(1−f(k))W(k
′
,k)−f(k)(1−f(k
′
))W(k,k
′
)
]d (^3) k′
(2π)^3
Let us examine some simple cases where the integral on the right-hand side becomes simplified.