524 APPENDIX B. BOLTZMANN TRANSPORT THEORY
Elastic Collisions
Elastic collisions represent scattering events in which the energy of the electrons remains un-
changed after the collision. Impurity scattering and alloy scattering discussed in Chapter 8 fall
into this category. In the case of elastic scattering the principle of microscopic reversibility
ensures that
W(k,k
′
)=W(k
′
,k) (B.25)
i.e., the scattering rate from an initial statekto a final statek
′
is the same as that for the reverse
process. The collision integral is now simplified as
∂f
∂t
)
scattering
=
∫ [
f(k
′
)−f(k)
]
W(k,k
′
)
d^3 k
′
(2π)^3
=
∫ [
g(k
′
)−g(k)
]
W(k,k
′
)
d^3 k
′
(2π)^3
(B.26)
The simple form of the Boltzmann equation is (from equation B.17)
−∂f^0
∂Ek
vk·eE =
∫
(gk−gk′)W(k,k
′
)d^3 k
′
=
−∂f
∂t
)
scattering
(B.27)
The relaxation time was defined through
gk =
(
−∂f^0
∂E
)
eE·vk·τ
=
−∂f
∂t
)
scattering
·τ (B.28)
Substituting this value in the integral on the right-hand side, we get
−∂f^0
∂Ek
vk·eE=
−∂f^0
∂Ek
eτE·
∫
(vk−vk′)W(k,k
′
)d^3 k
′
(B.29)
or
vk·E=τ
∫
(vk−vk′)W(k,k
′
)d^3 k
′
·E (B.30)
and
1
τ
=
∫
W(k,k
′
)
[
1 −
vk′·E
vk·E
]
d^3 k
′
(B.31)
In general, this is a rather complex integral to solve. However, it becomes considerably sim-
plified for certain simple cases. Consider, for example, the case of isotropic parabolic bands and
elastic scattering. In figure B.4 we show a geometry for the scattering process. We choose a
coordinate axis where the initial momentum is along thez-axis and the applied electric field is