Chapter 7 Laboratory: Solubility and Solutions 125
SvABLET ERSUS UNSTABLE
Before you make up a stock solution—particularly a
standardized stock solution—check to make sure that
the chemical is stable in solution. Some chemicals break
down in solution, and others react with the container
or air. For example, sodium hydroxide solutions absorb
carbon dioxide from the air, which converts some of the
sodium hydroxide to sodium carbonate. Sodium hydroxide
solutions also dissolve glass containers, further changing
the concentration and introducing contaminants. The best
practice is to make up solutions of such chemicals only as
needed. If you must make up stock solutions of unstable
chemicals, at least make the minimum amounts possible
and store them in inert plastic accordion bottles, such as
those sold by photography supply stores. Opaque, screw-
cap Nalgene bottles are also good for storage.
EvdRE y Ay SoLUTIoNS
We’re surrounded by solutions, quite literally, because
the atmosphere itself is a solution. You can find many
other examples of commonplace solutions just by
looking around you:
- An average home contains hundreds of solutions,
from beverages, vinegar, lemon juice, maple syrup,
and vanilla extract in the kitchen to the bleach
and fabric softener in the laundry room and the
medicines and personal care products in the
bathroom. - When you turn the key to start your car, the power
needed to crank the engine is supplied by a solution
of sulfuric acid in the car battery. When the engine
starts, it’s fueled by gasoline, which is a complex
solution of hydrocarbons and additives. - When you record a television program to a rewritable
DVD, your DVD recorder stores that program by
melting small pits into the complex solid solution
of rare-earth metals that makes up the recording
surface of the disc. - Our bodies are made up largely of water, which
serves as the solvent for the many complex solutions
that serve various functions in our bodies. For
example, our blood plasma is a complex solution of
proteins, salts, glucose and other carbohydrates,
amino acids, hormones, vitamins, gases, and
metabolic waste products. Cytosol, the fluid inside
our cells, is a similarly complex solution.