176 10 Multipole Potentials
As expected, this force is also obtained as a spatial derivative of the energyW,as
given by (10.45), viz.
Fμ=−∇μW(r). (10.48)
Notice, there is no force acting on an electric dipole moment subjected to a homo-
geneous electric field with∇μEν=0.
A torque, however is exerted on an electric dipole in a spatially constant electric
field. For discrete charges, the torque isTμ=εμνλ
∑
jr
j
νEλ(r+rj). The correspond-
ing expression for a continuous charge density is
Tμ=εμνλ
∫
r′νEλ(r+r′)d^3 r′. (10.49)
The torque can be expanded by analogy to (10.47). The leading term is
Tμ=εμνλpνelEλ(r). (10.50)
10.4.5 Multipole–Multipole Interaction
The multipole–multipole interaction of a cloud 1 of charges, located around the
positionr, in a potential and electric field generated by a group of charges 2, centered
around the positionr=0, can be inferred from (10.31) with (10.33) and (10.45). The
corresponding total charges are byQ 1 ,Q 2. The electric dipole moments and electric
quadrupole moment tensors are denoted byp(μ^1 ),pμ(^2 ), andQ(μν^1 ),Q(μν^2 ), respectively.
Thepole–pole,thepole–dipoleand thepole–quadrupoleinteraction energies are
Wpole−pole=
1
4 πε 0
Q 1 r−^1 Q 2 ,
Wpole−dip=
1
4 πε 0
Q 1 Xμpμ(^2 )=
1
4 πε 0
Q 1 r−^3 rμp(μ^2 ), (10.51)
Wpole−quad=
1
4 πε 0
1
6
Q 1 XμνQ(μν^2 )=
1
4 πε 0
1
2
Q 1 r−^5 rμrνQ(μν^2 ). (10.52)
Just as the pole–quadrupole interaction, the dipole–dipole interaction is governed by
the second multipole potential tensor, which decreases, with increasing distancer,
liker−^3 ,
Wdip−dip=−
1
4 πε 0
1
2
p(μ^1 )Xμνp(ν^2 )=−
1
4 πε 0
3
2
r−^5 pμ(^1 )rμrν p(ν^2 ). (10.53)