688 Chapter 12. Radiation Spectroscopy
Eγ Eγ Eγ
Photoelectron Energy
Photoelelectron Intensity
1s
2s
2p
−Eb,1s −Eb,2s −Eb,2p
Figure 12.1.14: A simple XPS photoelectron spectrum.
Each peak corresponds to emission of photoelectrons from
an atomic level. A typical spectrum contains a number of
peaks corresponding to different elements in the sample.
Sample
Vacuum
Pump
DetectorElectron Output
Trajectory
Electron
Focusing
Lenses
Hemispherical
Deflection Assembly
X−ray Source
Enclosure
Vacuumed
Figure 12.1.15: Conceptual design of an electron energy ana-
lyzer.
of a series of focusing lenses. These lenses perform two tasks. The first one is to
focus the electrons to the center of the slit to minimize their loss. The other task is
to slow down the electrons such that they fall within the required energy passband
of the analyzer. This slowing down is however not arbitrary since then the energy
information will be lost. The second main component of an HDA consists of two
metallic hemispheres. Application of electric potentials on these hemispheres creates