Advices For Studying Organic Chemistry
Solomons/SoloCh01 1.15 A SUMMARY OF IMPORTANT CONCEPTS THAT COME FROM QUANTUM MECHANICS 1.15A. Atomic orbital (AO): AO correspo ...
Solomons/SoloCh01 5) Number of molecular orbitals: 6) Sigma bond (σ): 7) Pi bond (π): 1.15C. Hybrid atomic orbitals: sp^3 orbit ...
Solomons/SoloCh01 Figure 1.32 The bond angles of methane are 109.5°. 1.16B Ammonia Figure 1.33 The tetrahedral arrangement of th ...
Solomons/SoloCh01 1.16D Boron Trifluoride Figure 1.35 The triangular (trigonal planar) shape of boron trifluoride maximally sepa ...
Solomons/SoloCh01 1.17 REPRESENTATION OF STRUCTURAL FORMULAS HC H H C H H C H H O H Ball-and-stick model Dash formula CH^3 CH^2 ...
Solomons/SoloCh01 C H H CC H H H H O H H C H H CC H H H H O H H C H H H C C O H H H H H or or Equivalent dash formulas for isopr ...
Solomons/SoloCh01 2) Hydrogen atoms bonded to C are not shown. 3) All atoms other than C and H are indicated. CH 3 CHClCH 2 CH 3 ...
Solomons/SoloCh01 2-Methyl-1,3-butadiene (isoprene), C 5 H 8 CC H CH H C H C H H H H Cyclohexane, C 6 H 12 CC C C C C H H H H H ...
REPRESENTATIVE CARBON COMPOUNDS: FUNCTIONAL GROUPS, INTERMOLECULAR FORCES, AND INFRARED (IR) SPECTROSCOPY Structure Is Everythin ...
up HIV protease by binding to it (suicide inhibitor). 7) Merck chemists modified the structures to increase their water solubili ...
Ethene (ethylene): US produces 30 billion pounds (~1,364 萬噸) each year. Ethene is produced naturally by fruits such as tomatoes ...
O O Br Br Cl Capilin Dactylyne Synthetic alkynes: Ethinyl estradiol, its estrogenlike properties have found use in oral contrac ...
Two contributing Kekulé structures A representation of the resonance hybrid 1) The bonds are not alternating single and double b ...
1) The charges are typically on the order of 10–10 esu; the distance 10–8 cm. Figure 2.1 a) A ball-and-stick model for hydrogen ...
Figure 2.2 Charge distribution in carbon tetrachloride. Figure 2.3 A tetrahedral orientation Figure 2.4 The dipole moment of of ...
2.4A DIPOLE MOMENTS IN ALKENES Cis-trans alkenes have different physical properties: m.p., b.p., solubility, and etc. Cis-isome ...
2.5B PHENYL AND BENZYL GROUPS Phenyl group: or or C 6 H 5 – or φ– or Ph– or Ar– (if ring substituents are present) Benzyl gro ...
C OH This is the functional group of an alcohol Alcohols can be viewed in two ways structurally: (1) as hydroxyl derivatives of ...
H 3 C C CH 3 CH 3 O H OH 3 o Carbon tert-Butyl alcohol (a 3o alcohol) O H H H H CH 3 Norethindrone (an oral contraceptive that c ...
H N H H R N H H Ammonia An amine Amphetamine C 6 H 5 CH 2 CHCH 3 H 2 NCH 2 CH 2 CH 2 CH 2 NH 2 NH 2 Putrescine (a dangerous stim ...
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