Advices For Studying Organic Chemistry

(Wang) #1
CH 3 CHCH 3
Cl
OH
CH 3

Isopropylcyclohexane Chlorocyclopentane 2-Methylcyclohexanol


CH 3

CH 2 CH 3 Cl

CH 3
CH 2 CH 3

1-Ethyl-3-methylcyclohexane 4-Chloro-2-ethyl-1-methylcyclohexane
(not 1-ethyl-5-methylcyclohexane) (not 1-Chloro-3-ethyl-4-methylcyclohexane)



  1. When a single ring system is attached to a single chain with a greater number of
    carbon atoms, or when more than one ring system is attached to a single chain:


CH 2 CH 2 CH 2 CH 2 CH 3

1-Cyclobutylpentane 1,3-Dicyclohexylpropane


4.4B BICYCLIC COMPOUNDS


  1. Bicycloalkanes: compounds containing two fused or bridged rings.


Two-carbon
bridge

Two-carbon
bridge

One-carbon
bridge

A bicycloheptane

==

Bridgehead
H 2 C
H 2 C
CH

CH 2

CH 2

CH
CH 2

Bridgehead
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