Advices For Studying Organic Chemistry

(Wang) #1

  1. Name compounds containing a double bond and an alcohol group as alkenols (or
    cycloalkenols) and give the alcohol carbon the lower number.


CH 3 C

CH 3
CHCHCH 3
OH

5 4 3 2 1

OH

(^12)
3
CH 3
4-Methyl-3-penten-2-ol 2-Methyl-2-cyclohexen-1-ol



  1. The vinyl group and the allyl group.


H^2 CCH H^2 CCHCH^2
The vinyl group The allyl group


CC
Br

H

H

H
CC
CH 2 Cl

H

H

H

Bromoethene or 3-Chloropropene or
vinyl bromide (common) allyl chloride (common)



  1. Cis- and trans-alkenes:.


CC
Cl

H

Cl

H
CC
Cl

H

H

Cl

cis-1,2-Dichloroethene trans-1,2-Dichloroethene


4.6 NOMENCLATURE OF ALKYNES



  1. Alkynes are named in much the same way as alkenes ⇒ replacing -ane to -yne.

    1. The chain is numbered to give the carbon atoms of the triple bond the lower
      possible numbers.



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