Advices For Studying Organic Chemistry

(Wang) #1
H

H 3 C(H 2 C) 7

H

(CH 2 ) 12 CH 3

Muscalure (sex attractant of common housefly)

4) Many insect sex attractants have been synthesized and are used to lure insects
into traps as a means of insect control.

4.17 CHEMICAL REACTIONS OF ALKANES



  1. C—C and C—H bonds are quite strong: alkanes are generally inert to many
    chemical reagents.



  1. C—H bonds of alkanes are only slightly polarized ⇒ alkanes are generally
    unaffected by most bases.

  2. Alkane molecules have no unshared electrons to offer sites for attack by acids.

  3. Paraffins (Latin: parum affinis, little affinity).



  1. Reactivity of alkanes:

    1. Alkanes react vigorously with oxygen when an appropriate mixture is
      ignited —— combustion.

    2. Alkanes react with chlorine and brmine when heated, and they react
      explosively with fluorine.




4.18 SYNTHESIS OF ALKANES AND CYCLOALKANES


4.18A HYDROGENATION OF ALKENES AND ALKYNES


  1. Catalytic hydrogenation:

    1. Alkenes and alkynes react with hydrogen in the presence of metal catalysts such
      as nickel, palladium, and platinum to produce alkanes.



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