Advices For Studying Organic Chemistry

(Wang) #1

CCl 3 –CH 3 CF 3 –CHClBr
1,1,1-trichloroethane 2-bromo-2-chloro-1,1,1-trifluoroethane (Halothane)


2) Vinyl halides: a halogen atom is bonded to an sp^2 -hybridized carbon.
3) Aryl halides: a halogen atom is bonded to an sp^2 -hybridized aromatic carbon.

CC
X

X

A vinylic halide A phenyl halide or aryl halide



  1. Importantance of Organohalogen Compounds:

    1. Solvents:
      i) Alkyl halides are used as solvents for relatively non-polar compounds.
      ii) CCl 4 , CHCl 3 , CCl 3 CH 3 , CH 2 Cl 2 , ClCH 2 CH 2 Cl, and etc.




2) Reagents:
i) Alkyl halides are used as the starting materials for the synthesis of many
compounds.
ii) Alkyl halides are used in nucleophilic reactions, elimination reactions,
formation of organometallics,.and etc.

3) Refrigerants: Freons (ChloroFluoroCarbon)

4) Pesticides: DDT, Aldrin, Chlordan

C
CCl 3

Cl Cl

H

Cl

Cl

H

H 3 CCH 3

Cl

DDT Plocamene B
[1,1,1-trichloro-2,2- insecticidal activity against mosquito
bis(p-chlorophenyl)ethane] larvae, similar in activity to DDT

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