Cl Cl
Cl
Cl Cl
Cl
Cl Cl
Cl
Cl Cl
Cl Cl
Cl
Aldrin Chlordan
5) Herbicides:
i) Inorganic herbicides are not very selective (kills weeds and crops).
ii) 2,4-D: Kills broad leaf weeds but allow narrow leaf plants to grow unharmed
and in greater yield (0.25 ~ 2.0 lb/acre).
OCH^2 CO^2 H
Cl Cl
OCH^2 CO^2 H
Cl Cl
Cl
2,4-D 2,4,5-T
2,4-dichlorophenoxyacetic acid 2,4,5-trichlorophenoxyacetic acid
iii) 2,4,5-T: It is superior to 2,4-D for combating brush and weeds in forest.
iv) Agent Orange is a 50:50 mixture of esters of 2,4-D and 2,4,5-T.
v) Dioxin is carcinogenic (carcinogen –– substance that causes cancer),
teratogenic (teratogen –– substance that causes abnormal growth), and
mutagenic (mutagen –– substance that induces hereditary mutations).
Cl
Cl O
O
Cl
Cl
O
O
2,3,6,7-tetrachlorodibenzodioxin (TCDD) dioxane (1,4-dioxane)