Organic Chemistry

(Jacob Rumans) #1
EZ Notation

To a certain extent, the Z configuration can be regarded as thecis-isomer and the E as the
trans-isomers. This correspondence is exact only if the two carbon atoms are identically
substituted.


In general, cis-trans should only be used if each double-bonded carbon atom has a hydrogen
atom (i.e. R-CH=CH-R’).


IUPAC Gold book on cis-trans notation.^1


IUPAC Gold book on E-Z notation.^2


1 http://goldbook.iupac.org/C01093.html
2 http://goldbook.iupac.org/E01882.html

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