Organic Chemistry

(Jacob Rumans) #1

Diels-Alder reaction


Notice that the product retains the same basic cyclohexene structure. The substituents
simply extend from the ring.

Alkynes can also react as dienophiles.


Diels-AlderreactionscansometimesreversethemselvesthroughRetro-Diels-Alderreactions.
For example, dicyclopentadiene can be cracked to form 1,3-cyclopentadiene by thermal
dissociation. Retro reactions occur under situations where the fragments are stable by
themselves.

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