Exercises 197
EXERCISES
Press on, and faith will catch up with you. — Jean D’Alembert
5.1 Quantum Mechanics
- Which of the wave functions in Fig. 5.15 cannot have physical
significance in the interval shown? Why not? - Which of the wave functions in Fig. 5.16 cannot have physical
significance in the interval shown? Why not?
3. Which of the following wave functions cannot be solutions of
Schrödinger’s equation for all values of x? Why not? (a)
Asecx; (b) Atanx; (c) Aex
2
; (d) Aex
2
.
4. Find the value of the normalization constant Afor the wave
function Axex
(^2) 2
.
- The wave function of a certain particle is Acos^2 xfor
2 x2. (a) Find the value ofA. (b) Find the proba-
bility that the particle be found between x0 and x 4.
5.2 The Wave Equation
- The formula yAcos (txν), as we saw in Sec. 3.3, de-
scribes a wave that moves in the xdirection along a stretched
string. Show that this formula is a solution of the wave equa-
tion, Eq.(5.3). - As mentioned in Sec. 5.1, in order to give physically meaning-
ful results in calculations a wave function and its partial deriva-
tives must be finite, continuous, and single-valued, and in addi-
tion must be normalizable. Equation (5.9) gives the wave
function of a particle moving freely (that is, with no forces
acting on it) in the xdirection as
Ae(i)(Etpx)
where Eis the particle’s total energy and pis its momentum.
Does this wave function meet all the above requirements? If
not, could a linear superposition of such wave functions meet
these requirements? What is the significance of such a superpo-
sition of wave functions?
5.4 Linearity and Superposition
- Prove that Schrödinger’s equation is linear by showing that
a 1 1 (x, t)a 2 2 (x, t)
is also a solution of Eq. (5.14) if 1 and 2 are themselves
solutions.
5.6 Operators
- Show that the expectation values pxand xpare related by
pxxp
This result is described by saying that pand xdo not commute
and it is intimately related to the uncertainty principle.
- An eigenfunction of the operator d^2 dx^2 is sinnx, where n
1, 2, 3,.... Find the corresponding eigenvalues.
i
(a)(b)(c)
(d)(e)(f)
x
x
x
x
x
x
Figure 5.15
(a)(b) (c)
(d)(e) (f)
x
x x
x
x
x
Figure 5.16
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