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Chapter 7 | 401

Isentropic process:

where Pris the relative pressureand vris the relative spe-
cific volume. The function s° depends on temperature only.
The steady-flow workfor a reversible process can be
expressed in terms of the fluid properties as

For incompressible substances (vconstant) it simplifies to

The work done during a steady-flow process is proportional
to the specific volume. Therefore,vshould be kept as small
as possible during a compression process to minimize the
work input and as large as possible during an expansion
process to maximize the work output.
The reversible work inputs to a compressor compressing an
ideal gas from T 1 ,P 1 to P 2 in an isentropic (Pvkconstant),
polytropic (Pvnconstant), or isothermal (Pvconstant)
manner, are determined by integration for each case with the
following results:

Isentropic:

Polytropic:

Isothermal: wcomp,inRT ln ¬

P 2
P 1

wcomp,in

nR 1 T 2 T 12
n 1



nRT 1
n 1

ca

P 2
P 1

b

1 n 1 2>n
 1 d

wcomp,in

kR 1 T 2 T 12
k 1



kRT 1
k 1

¬ca

P 2
P 1

b

1 k 1 2>k
 1 d

wrevv 1 P 2 P 12 ¢ke¢pe

wrev


2

1

v dP¢ke¢pe

a

v 2
v 1

b
sconst.



vr 2
vr 1

a

P 2
P 1

b
sconst.



Pr 2
Pr 1

s° 2 s° 1 R ln ¬

P 2
P 1

The work input to a compressor can be reduced by using
multistage compression with intercooling. For maximum sav-
ings from the work input, the pressure ratio across each stage
of the compressor must be the same.
Most steady-flow devices operate under adiabatic condi-
tions, and the ideal process for these devices is the isentropic
process. The parameter that describes how efficiently a
device approximates a corresponding isentropic device is
called isentropicor adiabatic efficiency. It is expressed for
turbines, compressors, and nozzles as follows:

In the relations above,h 2 aand h 2 sare the enthalpy values at
the exit state for actual and isentropic processes, respectively.
The entropy balance for any system undergoing any
process can be expressed in the general form as

or, in the rate form,as

For a general steady-flow processit simplifies to

S

#
genam

#
eseam

#
isia

Q

#
k
Tk

S

#
inS

#
out¬¬S

#
gen¬¬dSsystem>dt

SinSout¬ ¬ Sgen¬¬¢Ssystem


hN

Actual KE at nozzle exit
Isentropic KE at nozzle exit



V 22 a
V 22 s



h 1 h 2 a
h 1 h 2 s

hC

Isentropic compressor work
Actual compressor work



ws
wa



h 2 sh 1
h 2 ah 1

hT

Actual turbine work
Isentropic turbine work



wa
ws



h 1 h 2 a
h 1 h 2 s

123
Net entropy transfer
by heat and mass

123
Entropy
generation

123
Change
in entropy

123
Rate of net entropy
transfer by
heat and mass

123
Rate of entropy
generation

123
Rate of change
in entropy

REFERENCES AND SUGGESTED READINGS

1.A. Bejan. Advanced Engineering Thermodynamics. 2nd
ed. New York: Wiley Interscience, 1997.
2.A. Bejan. Entropy Generation through Heat and Fluid
Flow. New York: Wiley Interscience, 1982.
3.Y. A. Çengel and H. Kimmel. “Optimization of Expansion
in Natural Gas Liquefaction Processes.”LNG Journal,
U.K., May–June, 1998.
4.Y. Çerci, Y. A. Çengel, and R. H. Turner, “Reducing the
Cost of Compressed Air in Industrial Facilities.”
International Mechanical Engineering Congress and
Exposition, San Francisco, California, November 12–17,
1995.

5.W. F. E. Feller. Air Compressors: Their Installation,
Operation, and Maintenance. New York: McGraw-Hill,
1944.
6.M. S. Moran and H. N. Shapiro. Fundamentals of
Engineering Thermodynamics. New York: John Wiley &
Sons, 1988.
7.D. W. Nutter, A. J. Britton, and W. M. Heffington.
“Conserve Energy to Cut Operating Costs.”Chemical
Engineering, September 1993, pp. 127–137.
8.J. Rifkin. Entropy. New York: The Viking Press, 1980.

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