Chapter 7 | 401Isentropic process:where Pris the relative pressureand vris the relative spe-
cific volume. The function s° depends on temperature only.
The steady-flow workfor a reversible process can be
expressed in terms of the fluid properties asFor incompressible substances (vconstant) it simplifies toThe work done during a steady-flow process is proportional
to the specific volume. Therefore,vshould be kept as small
as possible during a compression process to minimize the
work input and as large as possible during an expansion
process to maximize the work output.
The reversible work inputs to a compressor compressing an
ideal gas from T 1 ,P 1 to P 2 in an isentropic (Pvkconstant),
polytropic (Pvnconstant), or isothermal (Pvconstant)
manner, are determined by integration for each case with the
following results:Isentropic:Polytropic:Isothermal: wcomp,inRT ln ¬P 2
P 1wcomp,innR 1 T 2 T 12
n 1nRT 1
n 1caP 2
P 1b1 n 1 2>n
1 dwcomp,inkR 1 T 2 T 12
k 1kRT 1
k 1¬caP 2
P 1b1 k 1 2>k
1 dwrevv 1 P 2 P 12 ¢ke¢pewrev
21v dP¢ke¢peav 2
v 1b
sconst.vr 2
vr 1aP 2
P 1b
sconst.Pr 2
Pr 1s° 2 s° 1 R ln ¬P 2
P 1The work input to a compressor can be reduced by using
multistage compression with intercooling. For maximum sav-
ings from the work input, the pressure ratio across each stage
of the compressor must be the same.
Most steady-flow devices operate under adiabatic condi-
tions, and the ideal process for these devices is the isentropic
process. The parameter that describes how efficiently a
device approximates a corresponding isentropic device is
called isentropicor adiabatic efficiency. It is expressed for
turbines, compressors, and nozzles as follows:In the relations above,h 2 aand h 2 sare the enthalpy values at
the exit state for actual and isentropic processes, respectively.
The entropy balance for any system undergoing any
process can be expressed in the general form asor, in the rate form,asFor a general steady-flow processit simplifies toS#
genam#
eseam#
isiaQ#
k
TkS#
inS#
out¬¬S#
gen¬¬dSsystem>dtSinSout¬ ¬ Sgen¬¬¢Ssystem
hNActual KE at nozzle exit
Isentropic KE at nozzle exitV 22 a
V 22 sh 1 h 2 a
h 1 h 2 shCIsentropic compressor work
Actual compressor workws
wah 2 sh 1
h 2 ah 1hTActual turbine work
Isentropic turbine workwa
wsh 1 h 2 a
h 1 h 2 s123
Net entropy transfer
by heat and mass123
Entropy
generation123
Change
in entropy123
Rate of net entropy
transfer by
heat and mass123
Rate of entropy
generation123
Rate of change
in entropyREFERENCES AND SUGGESTED READINGS1.A. Bejan. Advanced Engineering Thermodynamics. 2nd
ed. New York: Wiley Interscience, 1997.
2.A. Bejan. Entropy Generation through Heat and Fluid
Flow. New York: Wiley Interscience, 1982.
3.Y. A. Çengel and H. Kimmel. “Optimization of Expansion
in Natural Gas Liquefaction Processes.”LNG Journal,
U.K., May–June, 1998.
4.Y. Çerci, Y. A. Çengel, and R. H. Turner, “Reducing the
Cost of Compressed Air in Industrial Facilities.”
International Mechanical Engineering Congress and
Exposition, San Francisco, California, November 12–17,
1995.5.W. F. E. Feller. Air Compressors: Their Installation,
Operation, and Maintenance. New York: McGraw-Hill,
1944.
6.M. S. Moran and H. N. Shapiro. Fundamentals of
Engineering Thermodynamics. New York: John Wiley &
Sons, 1988.
7.D. W. Nutter, A. J. Britton, and W. M. Heffington.
“Conserve Energy to Cut Operating Costs.”Chemical
Engineering, September 1993, pp. 127–137.
8.J. Rifkin. Entropy. New York: The Viking Press, 1980.cen84959_ch07.qxd 4/19/05 10:59 AM Page 401