Chemistry of Essential Oils

(Tuis.) #1

218. THE CHEMISTKY OF ESSENTIAL OILS


COMPARISON OP THE PHYSICAL PROPERTIES AND THE CHEMICAL COMPOSITION OP
PEPPERMINT OILS DISTILLED FROM THE FRESH LEAVES, FROM THE TOPS,
AND FROM THE ENTIRE FRESH HERB AT THE VARIOUS STAGES OF GROWTH
(continued).






DescriptionYear and
of Material.

1910.


Budding stage:
Herb

Leaves

Tops

Flowering stage:
Herb

Leaves

Tops

Fruiting stage:
Herb

Leaves

Tops

Physical Properties.

Colour, Odour and
Taste.

Dark golden; not
fragrant, minty
odour ; slightly bit
ter, pungent, minty
taste
Golden-yellow; faint
not especially
minty odour;
slightly bitter, pun-
gent taste
Golden-yellow; agree-
able, minty odour;
strong, pungent,
bitter, cooling taste
Pale yellow; mild
agreeable odour
fatty, strong, cool-
ing, pungent taste
Pale yellow : strong
minty odo ur;
slightly fatty, bit-
ter, pungent, cool-
ing taste
Pale yellow; frag-
rant, agreeable
odour; fatty, bitter,
pungent, cooling
taste
Yellowish green ;
very fragrant flow-
ery odour; very
bitter, slightly pun-
gent taste
Golden-yellow;
strong minty
odour; bitter, cool-
ing, slightly pun-
Greenish -yellow;
agreeable, flowery
odour; bitter,
slightly pungent,
cooling taste

Specific
Gravity.

3-9155


(^3) -9156



3
-9273

•9231


•9242


•9250



Rota-
tion,
50 mm.
Tube.

- 12-1


- 13-1



- 5-7


- 9 - 4


- 6-5


- 7



Refrac-
tion.

1
1-4718

(^1) 1-4710



1
1-4820

1-4753


1-4780


1-4712


1-4720


1*4738


Solubil-
ity in
80 per
Cent.
Alcohol.

4
.7

(^4) -6



2-66


•7


•8


•8



Chemical Composition
(per Cent.).

Free
Acid
cetic).

•86


•90


•13


-03


1-90


1-43


1-14


4-80


3-30


Ester
(Men-
thyl
Ace-
tate).

16-62


19-80


13*44


11-67


22*27


22-98


20^86


43-40


28-29


Menthol.

Free.

43-76


18-79


29-19


30-94


37-83


48-60


12-7


Total

56'85


34-89


39-78


40-13


68-88


66-71


29-14



1
At 22° C.
» At 24° C.

(^2) Turbid in 3 volumes or more.
4
Turbid in 4 volumes or more.

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