Chemistry of Essential Oils

(Tuis.) #1

COMPOSITE 301


Solidago rugosa yields 0*5 per cent, of an oil of the following
characters:—
Specific gravity £Lfjl 0*862
25
Optical rotation - 12° 8'
Refractive index 1-4800
Saponification value 4-2
„ „ (after acetylation) 11
It contains pinene and limonene.
Solidago Caroliniana yields an oil which has been examined by
Eussell.
1
The fresh herb, gathered before flowering, yielded 0*693 per
cent, of oil having the following characters :—
Specific gravity at 23° 0-8587
Optical rotation - 10° 48'
Refractive index 1-4805
Ester value 6-35
„ „ (after acetylation) 25-3

It consists mainly of dipentene. It also contains pinene, limonene, an
aldehyde in traces, and acetic and formic acids in the form of esters.

OIL OF BLUMEA BALSAMIFEBA.

Bltimea Lasamifera is a plant indigenous to India, and is also found
freely in the Malay Archipelago. The essential oil has been examined
by Jonas,^2 who found it to have the following characters :—
Specific gravity 0*950
Optical rotation - 12° 30'
Refractive index 1'4815
Acid value 23-4
Ester 1
„ „ (after acetylation) 198
He has identified the following compounds in the oil: cineol,
limonene, palmitic and myristic acid in traces, 5 per cent, of a phenol
not definitely identified, Z-borneol, Z-camphor, and a sesquiterpene and a
sesquiterpene alcohol. The phenolic body present is probably phloro-
glucintrimethyl ether.

OIL OF PLUCHEA FOETIDA.

The fresh herb, Pluchea foetida, which is common in the southern
parts of the United States, yields 0'025 per cent, of an essential oil,
which has been examined by Eabak
3
and found to have the following
characters:—
Specific gravity 0-933
Optical rotation - 10'8
Refractive index 1-4832
Acid value 4
1
Ester 44
„ „ (after acetylation) 104
It contains cineol.
1
Jour. Am&r. Chem. Soc., 38 (1916), 1398.
3 * Schimmel's Bericht, April, 1909, 149.
Mid. Drug, and Ph. Rev., 45 (1911), 485.

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