Chemistry of Essential Oils

(Tuis.) #1

MYRTACEJE 373


culated as geranyl acetate, or 8
*
32 per cent, on the original oil. An
ester determination on the original oil gave 8'6 per cent.
A portion of the non-aldehydic oil was acetylated in the usual way,
and this gave a saponification number 78*47, which represents 15'14
per cent, of free alcohol, or 12*72 per cent, of geraniol in the original oil.
The oil of Eucalyptus Staigeriatia may be stated to have approxi-
mately the following constitution :—
Limonene
Geraniol
Geranyl acetate
Citral
Undetermined

60-00 per cent.
12-72
8-32
16*00
2-96

100-00

OIL OF EUCALYPTUS STELLULATA.
This oil has the following characters:—
Specific gravity 0-871
Optical rotation - 26*1°
Refractive index.1 '4902 at 16°
Yield 0-3 per cent.
It contains phellandrene, a sesquiterpene, and traces of eucalyptol.

OIL OF EUCALYPTUS STEICTA.
This oil has the following characters :—
Specific gravity 0*9246
Optical rotation - 3*4°
Refractive index 1-4711 at 16°
Yield 0*5 per cent.
It contains pinene, eucalyptol, and eudesmol.

OIL OF EUCALYPTUS STUAKTIANA.
This oil has the following characters :—
Specific gravity ........ 0*916
Optical rotation + 4*7°
Refractive index 1-4790 at 16°
Yield 0-4 per cent.
It contains about 50 per cent..of eucalyptol, pinene, and some esters.

OIL OF EUCALYPTUS T^ENIOLA.
This oil has the following characters :—•
Specific gravity 0-8864
Optical rotation - 27-6°
Refractive index 1-4872 at 17°
Yield 0-66 per cent.
It contains 7 per cent, of eucalyptol, phellandrene, eudesmol,
piper itone, and a sesquiterpene.


OIL OF EUCALYPTUS TERETICOKNIS.
This oil has the following characters:—
Specific gravity 0*9218
Optical rotation - 9 *3°
Refractive index.. 1*4934 at 16°
Yield 0-48 per cent.
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