Chemistry of Essential Oils

(Tuis.) #1

CONIFEE^B


Seven samples gave the results set out in Table I, and five of these
samples yielded fractionation results as set out in Table II.


TABLE I.

No.

1 2 3 4 5 6 7


Specific Gravity,
°C.

0-8729 (CL 18


0-8665 ,


0-8631 ,


0-8659 ,


0-8657 ,


0-8665 ,


0-8782 ,


. 18


, 24


, 17


719


, 24


, 24


Rotation
«
D.

+ 27-9°
+ 31-3°
+ 30-8°
+ 28-4°
+ 31-25°
+ 25-2°
+ 22-7°

Retractive Index,
°C.

1-4747® 18
1-4779 „ 16
1-4755 „ 20
1-4774 „ 19
1-4749 „ 19
1-4720 „ 24
1-4774 „ 19

Ester,
per Cent.

16-46


11-96


12*76


12-10


13-27


14-07


14-21


Yield,
per Cent.

0-562


0-616


0-610


0-635


0-569


0-563


0-532


TABLE II.

No.

1


2


3


4


5


1st.

156-160°


30°


156-161°


30°


Below 160°
27°/ 0
Below 161°
27%
Below 160°
28%

Fractious.

2nd.

160-175°


45%


161-165°


22%


160-165°


37%


161-165°


27%


160-165°


28%


3rd.

175-200°


8%


165-200°


37%


165-180°


16%


165-200°


31%


165-200°


32%


4th.

200-230°


12%


200-228°


6%


180-225°


12%


200-225°


7%


200-225°


77c

Specific Gravity and Rotation of
Fractious.

1st.

•8562


+ 30-4


•8545


+ 32-6


•8477


+ 32-4


•8550


+ 30-5


•8529


+ 32-2


2nd.

•8571


+ 27-2


•8555


+ 32


•8494


+ 31-6


•8565


+ 29-3


•8537


+ 31-7


3rd.

•8689


+ 21-0


•8649


+ 30-7


•8561


+ 80-5


•8664


+ 27-2


•8649


+ 30-6


4th.

•9415


+ 32-4


•9434


+ 33-5


•9256


+ 34-2


•9416


+ 32


•9322


+ 32-5


CALLITRIS ARENOSA.
The oil from the leaves of this tree resembled ordinary pine-needle
oil in odour, but had a marked suggestion of lemon. The principal con-
stituent was limonene, dextro-limonene preponderating. Two specimens
had the following characters :—

Specific
Gravity, ° C.

0-8491 @ 23


0-8452 ® 26


Rotation,
«D.

+ 35-8°


+ 18-9°


Refractive
Index,° C.

1-4760® 23


1-4764 @ 26


Ester,
per Cent.

5-17


3-57


Yield,
per Cent.

0-402


0-294


CALLITRIS INTRATROPICA.
The leaf oil is practically a terpene oil, the principal constituents
being pinene, dipentene, and laevo-limonene. Bornyl and geranyl esters
are present in very small amount. Two samples gave the following
values:—
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