426 DAIRY CHEMISTRY AND BIOCHEMISTRY
Table 10.10 General properties of emulsifying salts in relation to cheese processing (from Fox
et al., 1996a,b)
Orthophos- Pyrophos- Polypho-
Property Citrates phates phates sphates Aluminium
Ion exchange
(calcium
sequesterization)
in the pH range
Buffering action
5.3-6.0
para-Caseinate
Emulsification
dispersion
Bacteriostatic
Low Low Moderate High-very Low
high
High High Moderate Low-very -
low
Low Low High Very high -
Low Low Very high Very high Very low
(n = 3-10)
-low
high
Nil Low High High-very -
Table 10.11 Chemical, mechanical and thermal parameters as regulating factors in the cheese
processing procedures (from Caric and Kalab, 1993)
Process conditions Processed cheese block Processed cheese slice Processed cheese spread
Raw material
a. Average of cheese
b. Water-insoluble
N as a % of
total N
c. Structure
Emulsifying salt
Water addition
Temperature
Duration of
processing (min)
PH
Agitation
Reworked cheese
Milk powder or
whey powder
Homogenization
Filling (min)
Cooling
5-12%
Young to medium ripe,
predominantly young
75-90%
Predominantly long
Structure-building,
not creaming, e.g.
high molecular weight
polyphosphate, citrate
10-25% (all at once)
80-85’C
4-8
5.4-5.7
Slow
0-0.2%
None
5-15
Slowly (10-12 h)
at room temperature
Predominantly young Combination of young,
medium ripe, overipe
80-90% 60-75%
Long Short to long
Structure-building, Creaming, e.g. low and
not creaming, e.g.
phosphate/citrate polyphosphate
mixtures
medium molecular weight
5- 15% (all at once)
4-6 8-15
5.6-5.9 5.6-6.0
Slow Rapid
0 5-20%
0 0
20-45% (in portions)
78-85°C 85-98°C (150’C)
None Advantageous
As fast as possible 10-30
Very rapid Rapidly (15-30 min) in
cool air