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Laboratory Methods of Inorganic Chemistry, 2nd English Ed. 1928

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XIV TABLE OF CONTENTS.


CHAPTER VII.



  • INTRODUCTORY REMARKS ON LABORATORY PRACTICE PAGE

  • The Periodic Classification of the Elements CHAPTER I.

  • The Elements

    • REDUCTION OF OXIDES WITH CARBON



        1. Lead from Lead Oxide





    • ALUMINOTHERMY



        1. Manganese from Pyrolusite





        1. Chromium from Chromic Oxide





        1. Crystallized Silicon





        1. "Crystallized Boron"





    • REDUCTION WITH POTASSIUM CYANIDE



        1. Tin from Cassiterite; Melting-Point Determination





        1. Pure Antimony from Basic Antimony Chloride





    • REDUCTION WITH AQUEOUS REDUCING AGENTS



        1. Selenium Dioxide and Pure Selenium from Crude Selenium...





        1. Extraction of Gold





    • DESULPHURIZATION OF SULPHIDES BY THE PRECIPITATION PROCESS.



        1. Antimony from Stribnite





        1. Mercury from Cinnabar; Sodium and Ammonium Amalgams.





    • ROASTING PROCESSES



        1. Lead from Galena





    • CUPELLATION

      • 13.. Pure Silver from Coin Metal



    • METALS BY ELECTROLYSIS



        1. Lithium from Fused Lithium Chloride







  • Changes of Condition CHAPTER II.

    • POLYMERIZATION AND DISSOCIATION

    • ALLOTROPY



        1. Allotropy of Silver Sulphide '





        1. Allotropic Modifications of Sulphur

          • Mercuriiodide 17. Transformation Point of Cuprous Mercuriiodide and of Silver









      1. Iodides of Bismuth PAGE





        1. Tin Tetraohloride 49. Bismuth Tribromide; Boiling-Point Determination 77J





        1. Silicon Tetrachloride





        1. Titanium Tetrachloride from Rutile





        1. Anhydrous Titanium Trichloride



      • (c) Sulphides

        • of the Boiling-Point 54. Phosphorus Pentasulphide; Thermoelectric Determination





        1. Black Mercuric Sulphide; Transformation into Cinnabar





        1. Sulphides of Tin





        1. Green Manganese Sulphide





        1. Titanium Disulphide



        • (d) Nitrides

          • oxamide 59. Hydrogen Cyanide, Mercuric Cyanide, Cyanogen, and Dithio-







        1. Boron Nitride





        1. Magnesium Nitride; Ammonia from the Atmosphere





        1. Chromium Nitride



        • (e) Phosphides





        1. Magnesium Phosphide



        • (/) Carbides

          • from Acetylene 64. Calcium Carbide; Acetylene from Calcium Carbide; Benzene









  • Compounds Containing a Complex Negative Component CHAPTER IV.

    • COMPOUNDS WITH HOMOGENEOUS COMPLEXES

      • (o) Peroxides



        1. Sodium Peroxide





        1. Barium Peroxide





          1. Hydrogen Peroxide



        • (b) .Polysulphides



          1. Ammonium Pentasulphide



        • (c) Polyhalides



          1. Ammonium Tribromide

            • Tribromide and Potassium Tri-iodide 70. Law of Distribution; Proof of the Existence of Potassium





        • (d) Polynitrides sium-iodine Tetrachloride Ill



          1. Sodium Hydrazoate from Sodamide





      • OXYACIDS AND THEIR SALTS

        • (o) Cyanates





        1. Potassium Cyanate; Urea from Ammonium Cyanate

          • (b) Oxy-halogen Acids and their Salts PAGE

            • sium Chlorate 74. Electrolytic Production of Sodium Hypochlorite and Potas-









          1. Potassium Perchlorate





          1. Iodic Acid and Iodic Anhydride; "Time Reaction"





          1. Potassium Iodate from Potassium Chlorate







        1. Potassium Bromate and Potassium Bromide



        • (c) Nitrites and Nitrates





        1. Sodium Nitrite from Sodium Nitrate





        1. Potassium Nitrate from Sodium Nitrate





        1. Silver Nitrate





        1. Bismuth Nitrate and Basic Bismuth Nitrate



        • (d) Manganates and Ferrates





        1. Potassium Permanganate by the Fusion Method





        1. Electrolytic Preparation of Potassium Permanganate





        1. Barium Ferrate



        • (e) Oxyacids of Sulphur and their Salts





        1. Sulphuric Acid from Pyrite by the Chamber Process

          • Nitrate 87. Reduction of Barium Sulphate and Preparation of Barium







        1. Antimony Sulphate





        1. Alum from Kaolin





        1. Sodium Thiosulphate





        1. Barium Dithionate





        1. Sodium Tetrathionate





        1. Hyposulphurous Acid





        1. Potassium Persulphate, Electrolytically



      • (f) Carbonates



        1. Sodium Carbonate (Ammonia-Soda Process)



        • (g) Acids and Salts of Phosphorus





        1. Barium Hypophosphite





        1. Phosphorous Acid







  • THIOACIDS AND THEIE SALTS



      1. Potassium Trithiocarbonate Solution (Reagent for Nickel)....





      1. Barium Trithiocarbonate





      1. Sodium Thioantimonate





      1. Potassium Ferric Sulphide





      1. Ammonium Copper Tetrasulphide

        • COMPOUNDS COMPLEX HALOGEN ACIDS AND THEIR SALTS. COMPLEX CYANOGEN







      1. Hydrofluosilicic Acid





      1. Potassium Titanium Fluoride





        1. Ammonium Plumbic Chloride. Lead Tetrachloride





        1. Potassium Lead Iodide







      1. Potassium Mercuric Iodide





      1. Potassium Cobalticyanide



          1. Hydroferrocyanic Acid PAGE






      - 110. Cobaltous Salt of Hydromercurithiocyanic Acid
      
   - 111. Potassium Cobaltothiocyanate
      
- 112. Cadmium Iodide (Autocomplex Compound)


    • NITBITO ACIDS AND THEIB SALTS



        1. Potassium Mercurinitrite





        1. Sodium Cobaltinitrite; Potassium Cobaltmitrile





        1. Potassium Tetranitrito-diammine-cobaltate





    • HETEBOPOLY ACIDS AND THEIB SALTS



        1. Ammonium Phosphomolybdate





        1. Silicotungstic Acid





    • OBGANOCOMPLEX COMPOUNDS



        1. Potassium Ferric Oxalate; Platinotypes





        1. Optical Rotation of Uranyl Lsevo-malate







  • Compounds Containing a Complex Positive Component CHAPTER V.

    • AMMONIUM COMPOUNDS AND SUBSTITUTED AMMONIUM COMPOUNDS



        1. Dissociation of Ammonium Chloride



        • Potassium; Acetoneoxime 121. Hydroxylamine Sulphate; Hydroxylaminedisulphonate of





        1. Hydrazine Sulphate; Monochloramine





        1. Semicarbazide Hydrochloride





          1. Millon's Base







    • METAL-AMMONIA COMPOUNDS



        1. Silver-ammonia Sulphate


        - phate 126. Tetramminecupric Sulphate and Ammonium Cupric Sul-




        1. Tetramminecupric Chloride





        1. Hexamminenickelous Bromide





        1. Carbonatotetramminecobaltic Nitrate





        1. Chloropentamminecobaltic Chloride from the preceding



      • 131.. Chloropentamminecobaltic Chloride from Cobalt Carbonate..



        1. Sulphate and Nitrate of the Chloropentammine Series





        1. Hexamminecobaltic Salts (Luteocobalt Salts)





        1. Aquopentamminecobaltic Salts (Roseocobalt Salts)





        1. Dibromotetramminecobaltic Bromide (Dibrompraseo Salt)..





        1. Dinitritotetramminecobaltic Salts (Flavocobalt Salts)





        1. Dinitritotetramminecobaltic Chloride (Croseocobalt Salt).


        - Salts 138. Comparison of the Isomeric Dinitritotetramminecobaltic




        1. Trinitritotriammine Cobalt


        - Chloride 140. Hexamminechromic Nitrate and Chloropentamminechromic




        1. Hexamminecobaltous Chloride





        1. a-Diamminedichlorocobalt PAGE





        1. /3-Diamminedichlorocobalt





    • HYDRATES

      • Eutectic Mixture of Barium Chloride Dihydrate and Water 144. Melting-Point Maximum for Magnesium Nitrate Hexahydrate;



        1. Calcium Sulphate Hemihydrate





        1. Hydrates of Sodium Sulphate; Supersaturated Solutions....





        1. Transition Point of Sodium Sulphate





        1. Isomeric Chromic Chloride Hydrates







  • Complex Non-Electrolytes CHAPTER VI.

    • ACID CHLORIDES



        1. Sulphuric Acid Dichloride and Sulphuric Acid Monochloride.





        1. Pyrosulphuric Acid Chloride





        1. Sulphurous Acid Chloride (Thionyl Chloride)





        1. Nitrosylsulphuric Acid





    • ESTERS



        1. Ethyl Nitrate





          1. Amyl Nitrite and Methyl Nitrite





          1. Symmetrical Diethyl Sulphite





          1. Unsymmetrical Diethyl Sulphite





          1. Triethyl Phosphate.







        1. Tetraethyl Silicate



      • METAL-ORGANIC COMPOUNDS



          1. Zinc Ethyl

            • Iodide 160. Lead Tetraphenyl by Grignard's Reagent; Diphenyl-lead







          1. Nickel Carbonyl



          • Minerals Preparation of Compounds of the Rare Elements from Their

            • Spectroscopic Tests for Rubidium and Other Metals 162. Lithium Carbonate from Lepidolite, Petalite or Spodumene.







          1. Beryllium Hydroxide from Beryl





          1. Basic Beryllium Acetate





            1. Columbium and Tantalum Compounds from Columbite







          1. Molybdenum Compounds from Molybdenite





          1. Tungsten Compounds from Wolframite





          1. Working up of Pitchblende and Testing for Radioactivity....





          1. Uranium Compounds





          1. Thorium Compounds from Monazite









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