Analytical Chemistry

(Chris Devlin) #1

(9) H = 0.415 cm; H = 482


(10) The packed column. The capacity factors for the capillary column are << 1.


(11) 33.62% methyl-n-butyrate


9.02% methyl-iso-valerate

15.64% methyl-n-octanoate

41.72% methyl-n-decanoate

(12) (a) k' asp = 1.5 k' caf = 1.87


(b) Nasp = 2130 Ncaf = 1804

(c) Nasp = 3463 Hcaf = 3879

(d) Rs = 1.51

(13) (a) 8000; (b) 18 000


(14) (a) methyl stearate 0.73; cholesterol 0.12; α-tocopherol 0.45; methyl oleate 0.73; squalene 0.82.


Chapter 5


(3) Potassium dichromate is a good selection as it will oxidize. Fe2+ but not Cl–


(4) N 2 O


(5) pH = 9 is the lowest for quantitative formation of Ag-EDTA. AtpH = 5, K' Agr = 5 only, whilst K' CuY


= 2.2 × 1012


(6) K'' = 1.3 × 1010 ; Yes.


(7) 33.5% Mg.


Chapter 6


(1) (a) –0.335 V; (b) –01143 V


(2) (a) 7.59 × 10 –^9 ; (b) –0.228


(3) 4.08, 3.73, 0.08%


(4) 47.95 cm^3 ; 47.935 cm^3


(5) 160


(6) 0.112%

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