Cliffs AP Chemistry, 3rd Edition

(singke) #1

In the benzene molecule, there are 9 single bonds (9σ) and 3 double bonds (3σand 3π) for a
total of 12 sigma bonds.



  1. Which one of the following does NOT exhibit resonance?


A. SO 2
B. SO 3
C. HI
D. CO 3 2-
E. NO 3 -

Answer: C


There are no alternative ways of positioning electrons around the HI molecule. If you missed
this question, refer to your textbook on the concept of resonance.


Note: Had you been given the choice, CH 3 Br, you would not choose it due to a possible
Baker-Nathan effect (no-bond resonance). In base, one result is protolysis:


  1. What type of hybridization would you expect to find in BCl 3?


A. sp
B. sp^2
C. sp^3
D. sp^3 d^2
E. No hybridization occurs in this molecule.

Br


H
+
+

H

H

C H Br


H

H

C


H H

H

H H

H

C

C

C C

C

C

Part II: Specific Topics

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