Cliffs AP Chemistry, 3rd Edition

(singke) #1
IV. Beryllium
A. There is generally not enough energy available in chemical reactions to
remove inner electrons, as noted by the significantly higher third ionization
energy.
B. The Be2+ion is a very stable species with a noble-gas configuration, so re-
moving the third outermost electron from beryllium requires significantly
greater energy.
V. Neon
A. Neon is an inert element with a full complement of 8 electrons in its valence
shell.
B. It is significantly more difficult to remove neon’s most loosely held electron
(I 1 ) than that of beryllium’s I 1. This trend is also noted when examining I 2 ’s
and I 3 ’s. Neon also has a greater nuclear charge than beryllium, which, if all
factors are held constant, would result in a smaller atomic radius.

(c) Restatement: Cl 2 (g) passed into separate containers of Be and Ne. What compounds
formed? Explanation.
The only compound formed would be BeCl 2 .The Be atom readily loses 2 electrons
to form the stable Be2+ion. The third ionization energy is too high to form Be3+. The
electron affinity of neon is very low because it has a stable octet of electrons in its va-
lence shell and the ionization energies of neon are too high.
(d) Restatement: Given the first three ionization energies of element X what compounds
is it most likely to form with C1 2?
The first ionization energy (I 1 ) of element X is relatively low when compared to I 2
and I 3. This means that X is probably a member of the Group I alkali metals. Thus,
the formation of X2+and X3+would be difficult to achieve. Therefore, the formula is
most likely to beXCl.


  1. Bromine reacts with a metal (M) as follows:


M(s) + Br 2 (g) →MBr 2 (s)

Explain how the heat of the reaction is affected by
(a) The ionization energy for the metal M
(b) The size of the atomic radius for the ion M2+

Answer


This question is probably best answered in the outline format, because you will try to show a
logical progression of concepts leading to two overall conclusions. Using the chart format
would become too complicated. This question should take about ten minutes to answer.


Ionic Bonding
Free download pdf