Cliffs AP Chemistry, 3rd Edition

(singke) #1

Step 4: Rewrite the equilibrium expression in terms of the single unknown.


K.. P

P
p^05035
CO

CO^2
==-
^h

Step 5: Rewrite this relationship in terms of the quadratic equation so that you can solve for the
unknown x, the pressure of the CO.


x^2 = 1.75 −0.50x

Putting this equation into the standard form, ax^2 + bx + c= 0, you get


x^2 + 0.50x−1.75 = 0

Step 6: Use the quadratic equation to solve for x.


...
x
21

0 50! 0 50^2 4 1 1 75
=

---
^

^^^
h

8 hhhB

For Examples 4 and 5, use the following information:


A student prepared a 1.00 M acetic acid solution (HC 2 H 3 O 2 ). The student found the pH of the
solution to be 2.00.



  1. What is the Kavalue for the solution?


A 3.00 × 10 –7
B 2.00 × 10 –6
C 2.00 × 10 –5
D 1.00 × 10 –4
E 1.00 × 10 –3

Answer: D


Step 1: Write the balanced equation in a state of equilibrium.


HC 2 H 3 O2(aq)?H+(aq)+ C 2 H 3 O 2 – (aq)

Step 2: Write the equilibrium expression.


K
HC H O

HCHO
a 232

(^232)





    • 6
      77
      @
      AA
      Step 3: Use the pH of the solution to determine [H+].
      pH = −log[H+] = 2.00
      H+= 10–2.00 = 0.0100 M
      Part II: Specific Topics



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