Cliffs AP Chemistry, 3rd Edition

(singke) #1

  1. An oxide is known to have the formula X 2 O 7 and to contain 76.8% X by mass. Which of
    the following would you use to determine the atomic mass of X?


A.
.

.

.

16 0

23 2
2

7

76 8
ccmm#

B.
.

.

.

23 2

16 0
7

2

76 8
ccmm#

C.
.

.

.

16 0

23 2
7

2

76 8
ccmm#

D.
.

.

.

23 2

16 0
2

7

76 8
ccmm#

E..

.

.

76 8

23 2

16 0
2
ccmm#^7

Answer: C


From the information provided, you know that the oxide X 2 O 7 contains 76.8% X and 23.2%
oxygen by weight. If you had 100.0 g of the oxide, you would have 76.8 g of X and 23.2 g of O
(or 23.2/16.0 moles of O atoms). Because for each mole of O in the oxide you have 2/7 mole of
X, you have in effect (23.2/16.0) ×2/7 mole of X. Since the units of atomic mass are g/mole,
the setup is:


.

.

.

16 0

23 2
7

2

76 8
ccmm#

Finding the solution is unnecessary for selecting an answer; however, here is the solution for
your information.


./

.

.
/
g O mole O

gO
mole O

mole X

gX
g mol
16 0

23 2
7

2

76 8
186
#

=
e o e o

(The element is rhenium.)


Gravimetrics
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