Polymer Physics

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between air and water, and thus forming the cream with a relatively stable foam
structure. In recent years, the emergence of molecular gastronomy transplants the
lab physical chemistry into the food processing, to understand the molecular
mechanism and even to propose new recipes to meet the multiple functions of
food such as pretty, delicacy, tasty, hygiene, nutrition and healthy (This 2009 ;
Barham et al. 2010 ). In the near future, when a gastrologist elaborates on a specific
recipe, he may explain its physicochemical principles by using some knowledge of
polymer physics.


Question Sets



  1. Try to find one more example of the complex system from the emergentism point
    of view.

  2. Why can short chains of isotactic and atactic polypropylenes mix homo-
    geneously in the melt, while their long chains cannot?

  3. In the preparation of porous membranes, if one makes use of phase separation
    followed with crystalline solidification in polymer solutions to control the pore
    sizes, whether does the longer time for phase separation make larger sizes of
    pores?

  4. Surf the literature to learn the thermodynamic mechanism of DNA unwinding,
    and to list potentially important intramolecular and intermolecular contributions
    of enthalpy and entropy.


References


Anfinsen CB (1973) Principles that govern the folding of protein chains. Science 181:223–230
Barham P, Skibsted LH, Bredie WLP, Frøst MB, Møller P, Risbo J, Snitkjær P, Mortensen LM
(2010) Molecular gastronomy: a new emerging scientific discipline. Chem Rev
110:2313–2365
Cheng SZD (2008) Phase transitions in polymers. Elsevier, Amsterdam
Currey JD (2005) Hierarchies in biomineral structures. Science 309:253–254
Daggett V, Fersht AR (2003) Is there a unifying mechanism for protein folding. Trends Biochem
Sci 28:18–25
Ellis RJ (1997) Molecular chaperones: avoiding the crowd. Curr Biol 7:R531–R533
Flory PJ (1953) Principles of polymer chemistry. Cornell University Press, Ithaca
Graham PD, McHugh AJ (1998) Kinetics of thermally induced phase separation in a crystallizable
polymer solution. Macromolecules 31:2565–2568
Hu WB, Frenkel D (2005) Oriented primary crystal nucleation in lamellar diblock copolymer
systems. Faraday Discuss 128:253–260
Hu WB, Frenkel D (2006) Effect of the coil-globule transition on the free-energy barrier for intra-
chain crystal nucleation. J Phys Chem B 110:3734–3737
Hu WB, Mathot VBF (2003) Liquid-liquid demixing in a polymer blend driven solely by the
component-selective crystallizability. J Chem Phys 119:10953–10957
Hu WB, Mathot VBF, Frenkel D (2003a) Lattice model study of the thermodynamic interplay of
polymer crystallization and liquid-liquid demixing. J Chem Phys 118:10343–10348
Hu WB, Frenkel D, Mathot VBF (2003b) Free energy barrier to melting of single-chain polymer
crystallite. J Chem Phys 118:3455–3457


238 11 Interplay Between Phase Separation and Polymer Crystallization

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