262 Chapter 10
interference. Y capacitors have high electrical and
mechanical specifications so they are much less likely
to fail.
XY Capacitors. When used together they are called
XY capacitors.
10.2.4.7 Supercapacitors
Supercapacitors, Ultracapacitors, more technically
known as electrochemical double-layer capacitors, are
one more step beyond the electrolytic capacitors. The
charge-separation distance in ultracapacitors has been
reduced to literally the dimensions of the ions within the
electrolyte. In supercapacitors, the charges are not sepa-
rated by millimeters or micrometers (microns) but by a
few nanometers or from electrostatic capacitors to elec-
trolytic capacitors to ultracapacitors. The charge-separa-
tion distance has in each instance dropped by three
orders of magnitude, from 10–3m to 10–6m to 10–9m.
- How a Supercapacitor Works. An supercapacitor
or ultracapacitor, also known as a double-layer capac-
itor, polarizes an electrolytic solution to store energy
electrostatically. Though it is an electrochemical
device, no chemical reactions are involved in its
energy storage mechanism. This mechanism is highly
reversible and allows the ultracapacitor to be charged
and discharged hundreds of thousands of times.
An ultracapacitor can be viewed as two nonreac-
tive porous plates, or collectors, suspended within an
electrolyte, with a voltage potential applied across the
collectors. In an individual ultracapacitor cell, the
applied potential on the positive electrode attracts the
negative ions in the electrolyte, while the potential on
the negative electrode attracts the positive ions. A
dielectric separator between the two electrodes
prevents the charge from moving between the two
electrodes.
Once the ultracapacitor is charged and energy
stored, a load can use this energy. The amount of
energy stored is very large compared to a standard
capacitor because of the enormous surface area
created by the porous carbon electrodes and the small
charge separation of 10 angstroms created by the
dielectric separator. However, it stores a much
smaller amount of energy than does a battery. Since
the rates of charge and discharge are determined
solely by its physical properties, the ultracapacitor
can release energy much faster (with more power)
than a battery that relies on slow chemical reactions.
Many applications can benefit from ultracapaci-
tors, whether they require short power pulses or
low-power support of critical memory systems.
Using an ultracapacitor in conjunction with a battery
combines the power performance of the former with
the greater energy storage capability of the latter. It
can extend the life of a battery, save on replacement
and maintenance costs, and enable a battery to be
downsized. At the same time, it can increase avail-
able energy by providing high peak power whenever
necessary. The combination of ultracapacitors and
batteries requires additional dc/dc power electronics,
which increases the cost of the circuit.
Supercapacitors merged with batteries (hybrid
battery) will become the new superbattery. Just about
everything that is now powered by batteries will be
improved by this much better energy supply. They
can be made in most any size, from postage stamp to
hybrid car battery pack. Their light weight and low
cost make them attractive for most portable elec-
tronics and phones, as well as for aircraft and auto-
mobiles.
- Advantages of a Supercapacitor
- Virtually unlimited life cycle—cycles millions of
times—10 to 12 year life. - Low internal impedance.
- Can be charged in seconds.
- Cannot be overcharged.
- Capable of very high rates of charge and discharge.
- High cycle efficiency (95% or more).
- Virtually unlimited life cycle—cycles millions of
- Disadvantages of a Supercapacitor:
- Supercapacitors and ultra capacitors are relatively
expensive in terms of cost per watt. - Linear discharge voltage prevents use of the full
energy spectrum. - Low energy density—typically holds one-fifth to
one-tenth the energy of an electrochemical battery. - Cells have low voltages; therefore, serial connec-
tions are needed to obtain higher voltages, which
require voltage balancing if more than three
capacitors are connected in series. - High self-discharge—the self-discharge rate is
considerably higher than that of an electrochem-
ical battery. - Requires sophisticated electronic control and
switching equipment.
- Supercapacitors and ultra capacitors are relatively
A supercapacitor by itself cannot totally replace the
battery. But, by merging a supercapacitor and a battery
together—like a hybrid battery, it will be possible for