Quantum Mechanics for Mathematicians

(lily) #1

to agree with the opposite sign conventions for spatial and time translations in
the definitions of momentum and energy.
One finds for free particle solutions


ψ̂(k,ω) =√^1
2 π

∫∞

−∞

eiωte−i
21 mk^2 t ̃
ψ(k,0)dt

=δ(ω−

1

2 m

k^2 )


2 πψ ̃(k,0)

soψ̂(k,ω) will be a distribution onk−ωspace that is non-zero only on the
parabolaω= 21 mk^2. The space of solutions can be identified with the space of
functions (or distributions) supported on this parabola. Energy eigenstates of
energyEwill be distributions with a dependence onωof the form


ψ̂E(k,ω) =δ(ω−E)ψ ̃E(k)

For free particle solutions one hasE= k


2
2 m.
ψ ̃E(k) will be a distribution ink

with a factorδ(E−k


2
2 m).
For any functionf(k), the delta function distributionδ(f(k)) depends only
on the behavior offnear its zeros. Iff′ 6 = 0 at such zeros, one has (using linear
approximation near zeros off)


δ(f(k)) =


kj:f(kj)=0

δ(f′(kj)(k−kj)) =


kj:f(kj)=0

1

|f′(kj)|

δ(k−kj) (11.9)

Applying this to the case off(k) =E−k


2
2 m, with a graph that has two zeros,
atk=±



2 mEand looks like


− 2 mE


2 mE

E

k

f(k) =E−
k^2
2 m

Figure 11.1: Linear approximations near zeros off(k) =E−k

2
2 m
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