Quantum Mechanics for Mathematicians

(lily) #1

In the Dirac notation one has


ψ(qt,t) =〈qt|ψ(t)〉=〈qt|e−iHt|ψ(0)〉=〈qt|e−iHt

∫∞

−∞

|q 0 〉〈q 0 |ψ(0)〉dq 0

and the propagator can be written as


U(t,qt,q 0 ) =〈qt|e−iHt|q 0 〉

U(t,qt,q 0 ) can be computed for the free particle case by Fourier transform
of the momentum space multiplication operator:


ψ(qt,t) =

1


2 π

∫+∞

−∞

eikqtψ ̃(k,t)dk

=

1


2 π

∫+∞

−∞

eikqte−i

1
2 mk

(^2) t ̃
ψ(k,0)dk


=

1

2 π

∫+∞

−∞

eikqte−i
21 mk^2 t

(∫+∞

−∞

e−ikq^0 ψ(q 0 ,0)dq 0

)

dk

=

∫+∞

−∞

(

1

2 π

∫+∞

−∞

eik(qt−q^0 )e−i
21 mk^2 t
dk 0

)

ψ(q 0 ,0)dq 0

so


U(t,qt,q 0 ) =U(t,qt−q 0 ) =

1

2 π

∫+∞

−∞

eik(qt−q^0 )e−i
21 mk^2 t
dk (12.5)

Note that (as expected due to translation invariance of the Hamiltonian opera-
tor) this only depends on the differenceqt−q 0. Equation 12.5 can be rewritten
as an inverse Fourier transform with respect to this difference


U(t,qt−q 0 ) =

1


2 π

∫+∞

−∞

eik(qt−q^0 )U ̃(t,k)dk

where


U ̃(t,k) =√^1
2 π

e−i
21 mk^2 t
(12.6)

To make sense of the integral 12.5, the productitcan be replaced by a
complex variablez=τ+it. The integral becomes well-defined whenτ= Re(z)
(“imaginary time”) is positive, and then defines a holomorphic function inz.
Doing the integral by the same method as in equation 11.6, one finds


U(z=τ+it,qt−q 0 ) =


m
2 πz

e−

m
2 z(qt−q^0 )
2
(12.7)

Forz=τreal and positive, this is the kernel function for solutions to the
partial differential equation



∂τ

ψ(q,τ) =

1

2 m

∂^2

∂q^2

ψ(q,τ)
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