Quantum Mechanics for Mathematicians

(lily) #1

is known as “phase space”. Points in phase space can be thought of as uniquely
parametrizing possible initial conditions for classical trajectories, so another in-
terpretation of phase space is that it is the space that uniquely parametrizes
solutions of the equations of motion of a given classical mechanical system. The
basic axioms of Hamiltonian mechanics can be stated in a way that parallels
the ones for quantum mechanics.


Axiom(States).The state of a classical mechanical system is given by a point
in the phase spaceM=R^2 d, with coordinatesqj,pj, forj= 1,...,d.


Axiom(Observables).The observables of a classical mechanical system are the
functions on phase space.


Axiom(Dynamics).There is a distinguished observable, the Hamiltonian func-
tionh, and states evolve according to Hamilton’s equations


q ̇j=
∂h
∂pj

p ̇j=−
∂h
∂qj
Specializing to the cased= 1, for any observable functionf, Hamilton’s
equations imply


df
dt

=

∂f
∂q

dq
dt

+

∂f
∂p

dp
dt

=

∂f
∂q

∂h
∂p


∂f
∂p

∂h
∂q

We can define:


Definition(Poisson bracket).There is a bilinear operation on functions on the
phase spaceM=R^2 (with coordinates(q,p)) called the Poisson bracket, given
by


(f 1 ,f 2 )→{f 1 ,f 2 }=

∂f 1
∂q

∂f 2
∂p


∂f 1
∂p

∂f 2
∂q

An observablefevolves in time according to


df
dt
={f,h}

This relation is equivalent to Hamilton’s equations since it implies them by
takingf=qandf=p


q ̇={q,h}=

∂h
∂p

p ̇={p,h}=−

∂h
∂q

For a non-relativistic free particle,h=p

2
2 mand these equations become

q ̇=

p
m

, p ̇= 0
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