Quantum Mechanics for Mathematicians

(lily) #1

Note that these are not the momentum operatorsPthat act onH 1 , but are
operators in the quantum field theory that will be built out of quadratic com-
binations of the field operators. By equation 38.9 we want


e−ia·P̂Ψ(̂x)eia·P̂=Ψ(̂x+a)

or the derivative of this equation


[−iP̂,Ψ(̂x)] =∇Ψ(̂x) (38.10)

Such an operatorP̂can be constructed in terms of quadratic combinations of
the field operators by our moment map methods. We find (generalizing theorem
25.1) that the quadratic expression


μ−∇=i


R^3

Ψ(x)(−∇)Ψ(x)d^3 x

is real (since∇is skew-adjoint) and satisfies


{μ−∇,Ψ(x)}=∇Ψ(x), {μ−∇,Ψ(x)}=∇Ψ(x)

Using the Poisson bracket relations, this can be checked by computing for in-
stance (we’ll do this just ford= 1)


{μ−dxd,Ψ(x)}=i

{∫

Ψ(y)(−
d
dy

)Ψ(y)dy,Ψ(x)

}

=−i


{Ψ(y),Ψ(x)}
d
dy

Ψ(y)dy

=


δ(x−y)

d
dy

Ψ(y)dy=

d
dx

Ψ(x)

Quantization replaces Ψ,Ψ byΨ̂†,Ψ and gives the self-adjoint expression̂

P̂=


R^3

Ψ̂†(x)(−i∇)Ψ(̂x)d^3 x (38.11)

for the momentum operator. In chapter 37 we saw that, in terms of momentum
space annihilation and creation operators, this operator is


P̂=


R^3

pa†(p)a(p)d^3 p

which is the integral over momentum space of the momentum times the number-
density operator in momentum space.


38.3.2 Spatial rotations


For spatial rotations, we found in chapter 19 that these had as generators the
angular momentum operators


L=X×P=X×(−i∇)
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