Quantum Mechanics for Mathematicians

(lily) #1

~in the definition of the momentum operator. Our definitions ofSj and of
rotations using (see equation 6.3)


Ω(θ,w) =e−iθw·S=eθw·X

will not include these factors of~, but in any case they will be equivalent to
the usual physics definitions when we make our standard choice of working with
units such that~= 1.
States inH=C^2 that have a well-defined value of the observableSjwill be
the eigenvectors ofSj, with value for the observable the corresponding eigen-
value, which will be±^12. Measurement theory postulates that if we perform the
measurement corresponding toSjon an arbitrary state|ψ〉, then we will



  • with probabilityc+get a value of +^12 and leave the state in an eigenvector
    |j,+^12 〉ofSjwith eigenvalue +^12

  • with probabilityc−get a value of−^12 and leave the state in an eigenvector
    |j,−^12 〉ofSjwith eigenvalue−^12


where if


|ψ〉=α|j,+

1

2

〉+β|j,−

1

2


we have


c+=

|α|^2
|α|^2 +|β|^2

, c−=

|β|^2
|α|^2 +|β|^2

After such a measurement, any attempt to measure anotherSk,k 6 =jwill give
±^12 with equal probability (since the inner products of|j,±^12 〉and|k,±^12 〉are
equal up to a phase) and put the system in a corresponding eigenvector ofSk.
If a quantum system is in an arbitrary state|ψ〉it may not have a well-defined
value for some observableA, but the “expected value” ofAcan be calculated.
This is the sum over a basis ofHconsisting of eigenvectors (which will all
be orthogonal) of the corresponding eigenvalues, weighted by the probability
of their occurrence. The calculation of this sum in this case (A=Sj) using
expansion in eigenvectors ofSjgives


〈ψ|A|ψ〉
〈ψ|ψ〉

=

(α〈j,+^12 |+β〈j,−^12 |)A(α|j,+^12 〉+β|j,−^12 〉)
(α〈j,+^12 |+β〈j,−^12 |)(α|j,+^12 〉+β|j,−^12 〉)

=

|α|^2 (+^12 ) +|β|^2 (−^12 )
|α|^2 +|β|^2

=c+(+

1

2

) +c−(−

1

2

)

One often chooses to simplify such calculations by normalizing states so that
the denominator〈ψ|ψ〉is 1. Note that the same calculation works in general
for the probability of measuring the various eigenvalues of an observableA, as
long as one has orthogonality and completeness of eigenvectors.

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