208 Chapter 8
trapped by the zeolite and unable to come into contact with cellulose acetate,
the risk of autocatalysis is reduced.
5.3 Conservation of Plasticised PVC
The rate and extent of deterioration of plasticised PVC and the migration of
DEHP plasticiser are related. DEHP inhibits the degradation of the PVC poly-
mer, therefore when it either migrates to surfaces or is adsorbed by another
material, PVC materials discolour, become tacky to the touch and brittle.
Degradation may be inhibited by enclosing them in a non-adsorbent material
such as glass, containing non-agitated air. Calculations based on the weight
lost by model sheets during accelerated thermal ageing, and the rule of thumb
concerning the rate of reactions with temperature, indicate that the useful
lifetime of plasticised PVC objects may be prolonged more than 10-fold at
ambient conditions, by changing the storage environment from a polyethyl-
ene bag to a closed glass container. Enclosing plasticised PVC objects, what-
ever their level of deterioration, is inexpensive to implement, of low practical
complexity and allows public accessibility.
Figure 4Zeolite A4 adsorbs acetic acid from degrading cellulose acetate movie film